Alkanes (topic 12)

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1

What are the properties of Alkanes?

  • almost non-polar

  • Relatively non reactive (they burn and react with halogens under certain conditions

  • Insoluble (unable to form hydrogen bonds with water molecules)

  • Small alkanes are gases at room temperature

  • Larger alkanes (18 carbons) are solids at room temperature

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2

What is the formula for ring alkanes and why

C(n)H(2n)

There are no hydrogens on the end

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3

What is the angle of a straight chain

109.5 degrees

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4

What is the formula for a straight chain alkane

C(n)H(n+2)

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5

What does the pollutant Sulfur Oxide cause

Photochemical Smog and Acid rain

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6

Why are Sulfur Oxides Dangerous

They bond with the water vapour and the oxygen in the air to form sulfuric acid

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7

What creates excess Carbon Dioxide

  • Combustion

  • to generate energy

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8

Why is Carbon Dioxide dangerous

It is a greenhouse gas

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9

what are Particulates and what do they do

  • Carbon particles

  • they exacerbate asthma and cause cancer

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10

How is carbon monoxide formed and why is it dangerous

  • Carbon monoxide is formed through incomplete combustion (when the reaction does not have enough oxygen)

  • It is poisonous, bonds to the haemoglobin in your red blood cells and causes suffocation

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11

What is the order of a chain reaction

  • initiation

  • Propagation

  • Termination

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12

What is fracking

A process done to collect natural gas from within the rocks

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13

What are the pros of Fracking

  • increase the supply of gas (reduces imported gas and electricity)

  • Provides an alternative to coal

  • Creates Jobs

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14

What are the cons of fracking

  • Local area may be disturbed (means that one needs a social license to operate)

  • A large amount of water is used

  • Chemical additives pollute the water supplies

  • May cause earthquakes

  • The methane combusts

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15

What is the process of fracking

  • Shale is drilled into and pressurised

  • Water and sand are forced in to fracture the rock

  • HCl and Methanol are also added to break up shale and prevent corrosion

  • Gas is then collected

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16

What are the two types of cracking

  • catalytic

  • Thermal

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17

What are the conditions required for thermal cracking

High temperatures (700-1200K)

High pressure (7000 kPa / 70 atmospheres)

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18

What are the conditions required for catalytic cracking

  • Low pressure

  • high temperature (720 K)

  • a catalyst (zeolite)

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19

What is produced within thermal cracking

A high portion of Alkenes are produced

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20

How long is an alkane kept in the conditions for thermal cracking for and what happens if it is left in for too long?

  • one second

  • If left in for too long there will be too much decomposition

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