Chemistry Organics 3.5

0.0(0)
studied byStudied by 1 person
learnLearn
examPractice Test
spaced repetitionSpaced Repetition
heart puzzleMatch
flashcardsFlashcards
Card Sorting

1/64

flashcard set

Earn XP

Description and Tags

Study Analytics
Name
Mastery
Learn
Test
Matching
Spaced

No study sessions yet.

65 Terms

1
New cards

For an alcohol, name the group and name for a carbon chain length of 4

Group- OH

Butan-1-ol

2
New cards

For a haloalkane, name the group and name for a carbon chain length of 4

Group- X (halogen)
1-bromo butane

<p>Group- X (halogen)<br>1-bromo butane</p>
3
New cards

For an aldehyde, name the group and name for a carbon chain length of 4

Group- =O and H

Butanal

<p>Group- =O and H</p><p>Butanal </p>
4
New cards

For a ketone, name the group and name for a carbon chain length of 4

Group- =O and H

Butan-1-one

<p>Group- =O and H</p><p>Butan-1-one</p>
5
New cards

For a carboxylic acid, name the group and name for a carbon chain length of 4

Group- =O and OH

butanoic acid

<p>Group- =O and OH</p><p>butanoic acid</p>
6
New cards

For an amine, name the group and name for a carbon chain length of 4

group- -NH2

1-amino butane

<p>group- -NH2 </p><p>1-amino butane</p>
7
New cards

What does volatile mean?

A substance's tendency to evaporate or vaporize

8
New cards

For an ester, name the group and name for a carbon chain length of 4

group -COO
Butylbutanoate

<p>group -COO<br>Butylbutanoate</p>
9
New cards

For an acyl chloride, name the group and name for a carbon chain length of 4

group -COCl
butanoyl chloride

<p>group -COCl<br>butanoyl chloride</p>
10
New cards

For an amide, name the group and name for a carbon chain length of 4

CONH2
butanamide

<p>CONH2<br>butanamide</p>
11
New cards

What is included in an ester link

coo

12
New cards

What is included in an amide/peptide link?

CON(H)

<p>CON(H)</p>
13
New cards

What is included in an amino acid

H2N- -COOH

<p> H2N- -COOH</p>
14
New cards

For adding H2O test explain:

What the test is for…

Results…

Any extra notes…

Test for polar substances such as acids and alcohols, or for acid chlorides

Single layer- means substance is soluble (polar)

Double layer- means substance is in soluble (non-polar)

Acid chlorides spit and fume

15
New cards

For blue litmus test explain:

What the test is for…

Results…

Any extra notes…

Tests for acids and acid chlorides

Litmus turns red from liquid- acid

Litmus turns red from vapour- acid chloride

16
New cards

For red litmus test explain:

What the test is for…

Results…

Any extra notes…

Tests for amines

Litmus turns blue- amine

Note: amines react with water to make OH

17
New cards

For bromine water test explain:

What the test is for…

Results…

Any extra notes…

Tests for double and triple carbon-carbon bonds

Orange colour or Br2 disappears- double or triple bond present (unsaturated)

18
New cards

For neutral KMnO4 test explain:

What the test is for…

Results…

Any extra notes…

Tests for double and triple carbon bonds

Purple colour of KMnO4 changes to brown precipitate- double or triple bond present (unsaturated)

19
New cards

What does ppt stand for?

precipitate

20
New cards

For Cr2O72- test explain:

What the test is for…

Results…

Any extra notes…

Tests for alcohols and aldehydes

Orange solution turns green- alcohol or aldehyde present

Note: Tertiary alcohols don’t react

21
New cards

For MnO4- test explain:

What the test is for…

Results…

Any extra notes…

Tests for alcohols and aldehydes

Purple solution turns colourless- alcohol or aldehyde present

Note: Tertiary alcohols don’t react

22
New cards

For the Lucas test explain:

What the added solution includes…

What the test is for…

Results…

Any extra notes…

Concentrated HCl with ZnCl2 catalyst

Tests for primary, secondary and tertiary alcohols

Does not go cloudy- primary alcohol

Goes cloudy in about 15 minutes- secondary

Goes cloudy in less than a minute- tertiary

Note; cloudiness is due to formation of chloroalkane which is not soluble in the water present

23
New cards

For the Tollen’s reagent test explain:

What the added solution includes…

What the test is for…

Results…

Any extra notes…

alkaline [Ag(NH3)2]+

Tests for aldehydes, including glucose

Silver mirror forms on inside of tube- aldehyde present

Notes: ketones and alcohols don’t react

Aldehyde reduces Ag+ to Ag

24
New cards

For the Fehling’s reagent or Benedict’s solution test explain:

What the added solution includes…

What the test is for…

Results…

Any extra notes…

alkaline Cu2+ complex

Tests for aldehydes, including ketones

Red precipitate of Cu2O (or orange or yellow solution)- aldehyde present

Notes: ketones and alcohols don’t react

Aldehyde reduce Cu2+ to Cu+

25
New cards

For Na2CO3(aq) / NaHCO3(aq) test explain:

What the test is for…

Results…

Any extra notes…

Tests for carboxylic acids

Fizzing (CO2)- carboxylic acid present

Note: acid-carbonate

26
New cards

What are the 3 types of isomers?

Structural/constitutional, geometric, optical/stereo

27
New cards

Explain structural/constitutional isomers

Same empirical formula but different arrangement of atoms

28
New cards

Explain geometric isomers and requirements

Same empirical formula but different arrangement

Must have a double bond present and have different atoms (or groups of atoms) attached to the cs in the double bond

29
New cards

Explain optical/stereo isomers/ enantiomers and requirements

Same empirical formula but different arrangement

Must have 4 different groups attached to the central (chiral) carbon

30
New cards

Explain properties of alcohols

  • melting/boiling point (and compare to corresponding alkane)

  • polarity

  • solubility

  • melting and boiling points increase with increasing carbon chain length, higher than alkanes due to hydrogen bonding

  • polar, but polarity decreases with increasing carbon chain length

  • smaller alcohols (1-3c) are infinitely soluble in water, but larger alcohols are insoluble due to non-polar carbon chains

31
New cards

Explain hydrogen bonding:

The OH end of the alcohol is attracted to the H atom on a neighbouring molecule, resulting in a strong intermolecular attraction between the molecules that require more heat energy to break.

32
New cards

Fill in the gaps:

Water _______ alcohols such asc______ form ______ _________ bonds with water, which can ___________ the _____molecular attractions of the __________ molecules. Due to the length of the _______ chain, the _______ chain molecules have more ___________ ______ to ______ attractive forces.

Water soluble alcohols such as ethanol form strong hydrogen bonds with water, which can overcome the intermolecular attractions of the alcohol molecules. Due to the length of the carbon chain, the longer chain molecules have more temporary dipole to dipole attractive forces.

33
New cards

Finish the sentence:

For a substance to dissolve in water…

There must be an attraction between the molecule and the water molecule.

34
New cards

What is a long carbon chain on a molecule sometimes called in terms of solubility?

long hydrophobic ‘tail’

35
New cards

Explain properties of aldehydes

  • melting/boiling point (and compare to corresponding alkane)

  • polarity

  • solubility

Boiling point increases with increasing carbon chain length, higher than alkanes due to permanent dipole-dipole forces

polar, but polarity decreases with increasing carbon chain length

smaller aldehydes (1–4c) are soluble in water, but larger aldehydes are insoluble due to long hydrophobic (non-polar) carbon chain.

36
New cards

Explain properties of ketones:

  • melting/boiling point (and compare to corresponding alkane)

  • polarity

  • solubility

Boiling point increases with increasing carbon chain length, higher than alkanes due to permanent dipole-dipole forces

polar, but polarity decreases with increasing carbon chain length

smaller ketones (1-5c) are soluble in water due to hydrogen bonding, but larger alcohols are insoluble due to long hydrophobic (non-polar) carbon chain.

37
New cards

Explain a nucleophilic substitution reaction:

The bonds between the C and Cl and O atoms are polar because O and Cl are both very electronegative and therefore draw electrons away from from the carbon, creating a dipole on the carbon centre. This means the carbon centre is susceptible to ‘attacks’ from nucleophiles (substances such as water that have lone pairs of electrons).

38
New cards

What is hydrolysis in easy terms

Break a molecule using water

39
New cards

Explain properties of amines:

  • melting/boiling point (and compare to corresponding alkane)

  • polarity

  • solubility

Boiling point increases with increasing carbon chain length, higher than those of less polar compounds with similar molar masses.

polar, but polarity decreases with increasing carbon chain length

smaller amines (1-5c) are soluble in water due to hydrogen bonding, but larger alcohols are insoluble due to long hydrophobic (non-polar) carbon chain.

40
New cards

What is a polypeptide?

A polypeptide is formed from many amino acids with amides (peptide bonds) between the amino acids. H2N- CONH -COOH

<p>A polypeptide is formed from many amino acids with amides (peptide bonds) between the amino acids. H2N- CONH -COOH</p>
41
New cards

What type of molecule is a protein?

A protein is a polypeptide

42
New cards

Explain a condensation polymer:

A condensation polymer forms from the loss of a small molecule (eg HCl or H2O) and the monomers join together to form a long chain. A condensation polymer has an amide or ester bond.

43
New cards

What types of groups do molecules have to have for polyesters to form?

carboxylic acid or acid chloride and hydroxyl groups

44
New cards

What types of groups do molecules have to have for polyamides to form?

carboxylic acid and amine groups

45
New cards

What is formed when a carboxylic acid is added to alcohol

an ester link and H2O

46
New cards

What is formed when an acid chloride is added to alcohol

an ester link and HCl

47
New cards

What is formed when a carboxylic acid is added to an amine

peptide/amide link and H2O

48
New cards

Explain steps to making triglyceride (fat or oil)

Glycerol (propan,1,2,3-triol) + fatty acid (carboxylic acids) —> triglyceride + water

<p>Glycerol (propan,1,2,3-triol) + fatty acid (carboxylic acids) —&gt; triglyceride + water</p>
49
New cards

Explain steps of saponification (sodium salt)

Triglyceride + 3NaOH —> glycerol + soap (sodium salt)

<p>Triglyceride + 3NaOH —&gt; glycerol + soap (sodium salt)</p>
50
New cards

Give formula for hydrolysis reaction of an ester in acidic conditions:

Ester + H3O+ —> carboxylic acid + alcohol

51
New cards

Give formula for hydrolysis reaction of an ester in basic conditions:

Ester + OH- —> carboxylate ion + alcohol

52
New cards

Give formula for hydrolysis reaction of an amide in acidic conditions:

Amide + H3O+ —> carboxylic acid + ammonium ion (NH4+)

53
New cards

Give formula for hydrolysis reaction of an amide in basic conditions:

Amide + OH- —> carboxylate ion + NH3

54
New cards

What carboxylic acid derivative is the least reactive?

amides

55
New cards

Fill in the gaps:

Acid _________ exist as pungent, ______ liquids. They are ______ reactive substances. They have relatively ___ melting and boiling points because they do not have ________ bonding. Acid chlorides are not ______ but they react rapidly with water (spitting ______ ___ ______s).

Acid chlorides exist as pungent, fuming liquids. They are highly reactive substances. They have relatively low melting and boiling points because they do not have hydrogen bonding. Acid chlorides are not acidic but they react rapidly with water (spitting alcohol and amines).

56
New cards

Give formula for reaction of acid chloride and water and state what type of reaction this is:

RCOCl + H2O —> RCOOH + HCl
this is a nucleophilic substitution reaction

57
New cards

Acid + metal —>

salt + hydrogen

58
New cards

Acid + base —>

salt + water

59
New cards

Acid + metal carbonate —>

salt + water + carbon dioxide

60
New cards

What is a strong acid?

An acid which dissociates completely in solution

61
New cards

What is a weak acid?

An acid which only partially dissociates in solution

62
New cards

Are carboxylic acids weak or strong acids and what does this mean?

Carboxylic acids are weak acids so they only dissociate partially in solution

63
New cards

What is the formula for a haloalkane to amine reaction and name the type of reaction:

Haloalkane + NH3(alc) —> amine + hydrogen halide

64
New cards

Explain amine’s role as a base and how this affects it’s solubility:

Amines are weak bases and are similar to to ammonia in that they can behave as proton (H+) acceptors. The nitrogen atom has a lone pair of electrons that can bind to H+ to form an ammonium ion (NH4+). Smaller amines are soluble in polar solvents (eg water) due to attraction between the water molecules and these lone electron pairs.

65
New cards