Unit 6 Part 1 - Thermochemistry

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What needs to happen for something to melt/boil? What happens ot the energy of the system?

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1

What needs to happen for something to melt/boil? What happens ot the energy of the system?

For something to melt/boil, it requires in input of energy (endothermic).

The energy of the system increases.

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2

What needs to happen for something to freeze/condense? What happens ot the energy of the system?

For something to freeze/condense, it requires a release of energy (exothermic).

The energy of the system decreases.

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3

What happens when something goes through a phase change (change of state)?

It causes a change in potential energy, NOT kinetic energy. Therefore, the temperature of the system does not change.

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4

What is ΔHfusion?

It is the change in enthalpy of melting (+) or freezing (-); typical unit = kJ/mol.

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5

What is ΔHvaporization?

It is the change in enthalpy of boiling (+) or condensing (-); typical unit = kJ/mol

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6

Notice that BOTH exothermic/endothermic reactions have (the same/a different) magnitude (value) with opposite signs.

the same

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7

What happens when you have a positive “q” value from the heat capacity equation?

It means the energy of the system is increasing and is endothermic.

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8

What happens when you have a negative “q” value from the heat capacity equation?

It means the energy of the system is decreaseing and it is exothermic.

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9

What is the definition of specifc heat?

The amount of energy required to raise the temperature of one gram of a substance by one degree Celsius/Kelvin.

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10

Why is the specific heat different for every substance?

It is because the transfer of energy does not equal the same temperature change of different substances (at the same mass).

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11

What is true about particles in a warm body in terms of kinetic energy?

They have a higher average kinetic energy THAN particles in a cooler body.

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12

What happens when you pour particles from a warmer body into a cooler body?

Those warm particles, which are already moving faster, will make the cold particles move faster, increasing THEIR temperature, but decreasing the WARM particle temperature.

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13

Why does the average kinetic energy of warmer particles DECREASE when added to cooler particles?

It is because the warmer particle’s energy is transferred into the cooler particles.

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14

Energy lost by the system is absorbed by what?

the surroundings!

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15

What happens when things are being heated (endothermic) in terms of a physical change?

Heat goes into the system and therefore increases the temperature CAUSING melting/vaporizing, etc.

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16

What happens when things are being heated (endothermic) in terms of a chemical change?

The energy (heat) going into the system will break the bonds in the reactants, which will then be released by making new bonds in the products.

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