G. Watson Student_Notes AP Chem Unit 6

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20 Terms

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Thermochemistry

The study of the heat energy associated with chemical reactions and physical changes.

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Endothermic Reaction

A reaction that absorbs energy from its surroundings, resulting in a positive enthalpy change (∆H > 0).

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Exothermic Reaction

A reaction that releases energy to its surroundings, resulting in a negative enthalpy change (∆H < 0).

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Enthalpy (H)

A thermodynamic quantity that represents the total heat content of a system.

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Heat Transfer (q)

The amount of energy transferred as heat during a temperature change; calculated using q = c m ∆T.

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Calorimetry

The measurement of heat changes in physical and chemical processes using a calorimeter.

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Heat Capacity (C)

The amount of heat required to raise the temperature of a substance by 1 degree Celsius.

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Specific Heat Capacity (c)

The amount of heat required to raise the temperature of 1 gram of a substance by 1 degree Celsius.

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Thermal Equilibrium

A state in which two objects in thermal contact reach the same temperature.

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Bond Enthalpy

The energy required to break one mole of a particular type of bond in gaseous molecules, measured in kJ/mol.

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Molar Enthalpy of Formation

The heat change that results when one mole of a compound is formed from its elements in their standard states.

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Hess’s Law

The principle stating that the total enthalpy change for a reaction is the same, regardless of the number of steps in the reaction.

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Latent Heat

The heat required for a phase change, such as melting or vaporization, at constant temperature.

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Heat of Vaporization

The amount of energy needed to convert a liquid into a gas at its boiling point.

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Heat of Fusion

The amount of heat required to turn a solid into a liquid at its melting point.

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Kinetic Energy (KE)

The energy that an object possesses due to its motion, quantified as KE = ½mv².

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Potential Energy (PE)

The energy stored in an object due to its position or configuration.

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Thermal Energy

The total energy of the particles in a substance, related to temperature.

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Enthalpy Change (∆H)

The difference in enthalpy between products and reactants during a chemical reaction.

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Phase Change

A transition of matter from one state to another, such as from solid to liquid.

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