Polar Protic, Polar Aprotic Solvents, and Categorizing Reagents

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42 Terms

1
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Is H2O polar protic or polar aprotic

polar protic

2
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Is MeOH polar protic or polar aprotic

polar protic

3
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Is EtOH polar protic or polar aprotic

polar protic

4
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Is acetic acid polar protic or polar aprotic

polar protic

5
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Is NH3 polar protic or polar aprotic

polar protic

6
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Is dimethylsulfoxide (DMSO) polar protic or polar aprotic

polar aprotic

7
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Is dimethylformamide (DMF) polar protic or polar aprotic

polar aprotic

8
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Is hexamethylphosphoramide (HMPA) polar protic or polar aprotic

polar aprotic

9
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Is CH3C triple bonded to N/acetonitrile polar protic or polar aprotic

polar aprotic

10
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What is polar aprotic

contain no hydrogen atoms connected directly to an electronegative atom

11
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What is polar protic

contain at least one hydrogen atom connected directly to an electronegative atom

12
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Does polar aprotic/protic promote SN2 and E2

polar aprotic

13
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Does polar aprotic/protic promote SN1 and E1

polar protic

14
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Is Cl- a neucleophile, base, strong nuc/strong base, or weak nuc/weak base

neuclophile

15
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Is Br- a neucleophile, base, strong nuc/strong base, or weak nuc/weak base

nucleophile

16
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Is I- a neucleophile, base, strong nuc/strong base, or weak nuc/weak base

nucleophile

17
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Is HS- a neucleophile, base, strong nuc/strong base, or weak nuc/weak base

nucleophile

18
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Is RS- a neucleophile, base, strong nuc/strong base, or weak nuc/weak base

nucleophile

19
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Is H2S a neucleophile, base, strong nuc/strong base, or weak nuc/weak base

nucleophile

20
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Is RSH a neucleophile, base, strong nuc/strong base, or weak nuc/weak base

nucleophile

21
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Is H-(of NaH) a neucleophile, base, strong nuc/strong base, or weak nuc/weak base

base

22
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Is DBN a neucleophile, base, strong nuc/strong base, or weak nuc/weak base

base

23
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Is DBU a neucleophile, base, strong nuc/strong base, or weak nuc/weak base

base

24
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Is HO- a neucleophile, base, strong nuc/strong base, or weak nuc/weak base

strong nuc/strong base

25
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Is MeO- a neucleophile, base, strong nuc/strong base, or weak nuc/weak base

strong nuc/strong base

26
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Is EtO- a neucleophile, base, strong nuc/strong base, or weak nuc/weak base

strong nuc/strong base

27
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Is tert-butoxide a neucleophile, base, strong nuc/strong base, or weak nuc/weak base

strong nuc/strong base

28
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Is H2O a neucleophile, base, strong nuc/strong base, or weak nuc/weak base

weak nuc/weak base

29
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Is MeOH a neucleophile, base, strong nuc/strong base, or weak nuc/weak base

weak nuc/weak base

30
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Is EtOH a neucleophile, base, strong nuc/strong base, or weak nuc/weak base

weak nuc/weak base

31
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If you have a nucleophile and a primary alkene, what reaction would it be

SN2

32
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If you have a nucleophile and a secondary alkene, what reaction would it be

SN2 +SN1

33
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If you have a nucleophile and a tertiary alkene, what reaction would it be

SN1

34
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If you have a base and a primary alkene, what reaction would it be

E2

35
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If you have a base and a secondary alkene, what reaction would it be

E2

36
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If you have a base and a tertiary alkene, what reaction would it be

E2

37
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If you have a strong nuc/strong base and a primary alkene, what reaction would it be

E2 (minor) + SN2 (major)

38
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If you have a strong nuc/strong base and a secondary alkene, what reaction would it be

E2 (major) + SN2 (minor)

39
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If you have a strong nuc/strong base and a tertiary alkene, what reaction would it be

E2

40
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If you have a weak nuc/weak base and a primary alkene, what reaction would it be

SN2 + E2 (not practical)

41
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If you have a weak nuc/weak base and a secondary alkene, what reaction would it be

SN2 + SN1 + E2 + E1 (not practical)

42
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If you have a weak nuc/weak base and a tertiary alkene, what reaction would it be

SN1 + E1