Ochem Ch 19- Nucleophilic Addition to Aldehydes and Ketones

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41 Terms

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what is this product called?

imine

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what is this product called?

enamine

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no rxn

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mechanism of imine formation

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mechanism of enamine formation

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mechanism of acetal formation

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mechanism of formation of cyclic acetal

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mechanism of a conjugate addition to an alpha, beta unsaturated aldehyde or ketone

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what are some examples of nucleophiles that add to the beta carbon?

-water

-alcohol

-ammonia

-cyanide ion

-enolate

-primary and secondary amines

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what are some examples of nucleophiles that add to the carbonyl carbon?

-grignard reagents

-hydride reagents (LiAlH4 or NaBH4)

-alkyllithium species

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