Chapter 8 alkene rxns

Hydrohalogenation (Markovnikov)

Hydrohalogenation (Markovnikov)

addition of HX, X at more substituted position

Hydrohalogenation (anti-Markovnikov)

addition of HBr, ROOR - Br at less substituted position

Acid-catalyzed hydration

Addition of H3O+, Markovnikov

Oxymercuration-demercuration

Addition of Hg(OAc)2, H20 and NaBH4 - Markovnikov addition of H-OH

Hydroboration-oxidation

Addition of BH3 THF, H2O2 and NaOH, Addition of H-OH, anti-Markovnikov, syn addition

Hydrogenation

Addition H2 and a metal (Pt)

Bromination

Addition of Br2, Anti (trans)-addition

Halohydrin formation

Addition of Br2, H2O, anti-Markovnikov, Anti (trans) addition

Anti dihydroxylation

Addition of RCO3H and H3O+, Anti (trans) addition, addition of OH-OH

Syn Dihydroxylation (2 reactions)

Addition of KMnO4 and NaOH cold, Syn addition, addition of OH-OH

Addition of OsO4 and NaHSO3 and H2O, Syn addition, addition of OH-OH

Ozonolysis

Addition of C=O bonds, addition of O3 and DMS