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Stereochemistry
a 3D arrangement of atoms in space
Stereoisomers
molecules with the same connectivity but different arrangements of atoms in space
Enantiomers
non-superimposable mirror image isomers
Chiral
a molecule is ____ when a molecule cannot be superimposed on its mirror image
cis
happens when molecules are on the same side
trans
happens when molecules are on opposite sides
Achiral
any molecule with a plane of symmetry is _____
Opticallly Active
molecules enriched in an enantiomer will rotate plane polarized are said to be ______
Fischer Projections
are representations of 3D molecules as a flat structure
Enantiomers
will rotate plane-polarized light of the same magnitude but different directions
Diastereomers
are non-mirror images of stereoisomers that occur when there is more than one chiral center in a molecule
Meso
compounds that contain chiral atoms but are achiral because they have a plane of symmetry
Isomers
compounds with the dame chemical formula, but different arrangement of atoms
Constitutional Isomers
compounds that have different connectivities
Geometric Isomers
pairs of molecules with the same compounds attached to a double bond differently
Conformation Isomers
are molecules that can rotate the compounds within it