ALevel OCR A Chemistry - synthetic routes

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alkane to haloalkane mechanism

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1

alkane to haloalkane mechanism

radical substitution

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2

haloalkane to alcohol reagent

NaOH (aq)

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3

haloalkane to alcohol mechanism

nucleophilic substitution

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4

haloalkane to nitrile reagents

CN-/ethanol

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5

haloalkane to nitrile mechanism

nucleophilic substitution

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6

haloalkane to amine reagents

NH3/ethanol

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7

haloalkane to amine mechanism

nucleophilic substitution

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8

alcohol to alkene reagents

H3PO4/H2SO4 heat

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9

alcohol to alkene mechanism

elimination

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10

primary alcohol to aldehyde reagents

K2Cr2O7/H2SO4 distillation

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11

primary alcohol to carboxylic acid reagents

K2Cr2O7/H2SO4 reflux

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12

secondary alcohol to ketone reagents

K2Cr2O7/H2SO4 reflux

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13

nitrile to amine reagents

H2/Ni OR LiAlH

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14

nitrile to amine mechanism

nucleophilic addition

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15

nitrile to carboxylic acid reagents

H2O/HCl heat

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16

ketone to secondary alcohol reagents

NaBH4

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17

ketone to secondary alcohol mechanism

nucleophilic addition

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18

aldehyde to primary alcohol reagents

NaBH4

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19

aldehyde to primary alcohol mechanism

nucleophilic addition

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20

alcohol to ester reagents

carboxylic acid/conc H2SO4 OR acid anhydride

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21

ketone to hydroxynitrile reagents

NaCN(aq)/H+(aq)

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22

ketone to hydroxynitrile mechanism

nucleophilic addition

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23

hydroxynitrile to amine reagent

H2/Ni

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24

aldehyde to hydroxynitrile reagent

NaCN(aq)/H+(aq)

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25

aldehyde to hydroxynitrile mechanism

nucleophilic addition

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26

aldehyde to carboxylic acid reagent

K2Cr2O7/H2SO4 heat

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27

hydroxynitrile to carboxylic acid reagent

H2O/HCl heat

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28

ester to carboxylic acid reagent

dilute acid, heat

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29

carboxylic acid to ester reagent

alcohol, conc H2SO4

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30

carboxylic acid to acyl chloride reagent

SOCl2

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31

acyl chloride to carboxylic acid reagent

H2O

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32

acyl chloride to primary amide reagent

NH3

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33

acyl chloride to secondary amide reagent

primary amide

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34

acyl chloride to ester reagent

alcohol

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35

ester to carboxylate reagent

OH- heat

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36

benzene to methylbenzene reagent (alkylation)

CH3Cl/AlCl3

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37

benzene to methylbenzene mechanism (alkylation)

electrophilic substitution

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38

benzene to bromobenzene reagent

Br2 AlBr3/FeBr3

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39

benzene to bromobenzene mechanism

electrophilic substitution

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40

benzene to chlorobenzene reagent

Cl2 AlCl3/FeCl3

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41

benzene to chlorobenzene mechanism

electrophilic substitution

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42

benzene to phenylethanone reagent (acylation)

CH3COCl AlCl3

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43

benzene to phenylethanone mechanism (acylation)

electrophilic substitution

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44

phenylethanone to phenylethanol reagent

NaBH4

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45

benzene to nitrobenzene reagent

conc HNO3 conc H2SO4

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46

benzene to nitrobenzene mechanism

electrophilic substitution

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47

nitrobenzene to phenylamine reagent

Sn conc HCl

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48

phenylamine to 2,4,6-tribromophenylamine reagent

Br2

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49

phenylamine to 2,4,6-tribromophenylamine mechanism

electrophilic substitution

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50

phenol to 2,4,6-tribromophenol reagent

Br2

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51

phenol to 2,4,6-tribromophenol mechanism

electrophilic substitution

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52

phenol to sodium phenoxide reagent

NaOH(aq)

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53

phenol to 2-nitrophenol/4-nitrophenol

dilute HNO3

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54

alkene to alkane reagents

H2/Ni

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55

alkene to alkane mechanism

electrophilic addition

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56

alkene to haloalkane reagents

hydrogen halide

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57

alkene to haloalkane mechanism

electrophilic addition

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58

alkene to alcohol reagents

H2O (steam)/H3PO4

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59

alkene to alcohol mechanism

electrophilic addition

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60

alkane to haloalkane reagents

halogen/UV

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