Chemistry organic synthesis

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27 Terms

1
Alkene→ haloalkane
HX or X2
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2
Alkene → alkane
H2, Ni catalyst, heat
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3
Alkene → alcohol
Steam, H+, heat
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4
Alkane → haloalkane
X2, UV
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5
Alcohol → alkene
H+, heat
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6
Primary alcohol → aldehyde → carboxylic acid
K2Cr2O7, H+, distillation → aldehyde.

Reflux→ carboxylic acid
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7
Secondary alcohol→ ketone
K2Cr2O7, H+, reflux
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8
Alcohol→ haloalkane
NaX, H+, reflux
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9
Haloalkane → nitrile
NaCN
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10
Haloalkane → amine
NH3, ethanol
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11
Haloalkane → alcohol
NaOH, heat, reflux
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12
Alcohol → ester
carboxylic acid, H2SO4
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13
Carboxylic acid → ester
Alcohol, H2SO4
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14
Ester → carboxylate and alcohol
NaOH
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15
Ester → carboxylic acid
dilute acid
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16
carboxylic acid→ acyl chloride
SOCl2
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17
acyl chloride → carboxylic acid
H2O
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18
Aldehyde → hydroxynitrile
NaCN, H+
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19
Acyl chloride → primary amide
NH3
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20
Acyl chloride → secondary amide
Primary amine
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21
benzene→ methylbenzene
CH3Cl, AlCl3
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22
benzene→ halobenzene
X2, halogen carrier
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23
benzene→ phenylethanone
CH3COCl, AlCl3
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24
benzene → nitrobenzene
HNO3, H2SO4
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25
nitrobenzene→ phenylamine
Sn, HCl → NaOH
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26
phenylethanone → 1-phenylethanol
NaBH4/ \[H\]
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27
phenylamine → 2,4,6 tribromoaminobenzene.
3Br2
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