Chemistry organic synthesis

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27 Terms

1

Alkene→ haloalkane

HX or X2

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2

Alkene → alkane

H2, Ni catalyst, heat

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3

Alkene → alcohol

Steam, H+, heat

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4

Alkane → haloalkane

X2, UV

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5

Alcohol → alkene

H+, heat

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6

Primary alcohol → aldehyde → carboxylic acid

K2Cr2O7, H+, distillation → aldehyde.

Reflux→ carboxylic acid

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7

Secondary alcohol→ ketone

K2Cr2O7, H+, reflux

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8

Alcohol→ haloalkane

NaX, H+, reflux

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9

Haloalkane → nitrile

NaCN

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10

Haloalkane → amine

NH3, ethanol

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11

Haloalkane → alcohol

NaOH, heat, reflux

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12

Alcohol → ester

carboxylic acid, H2SO4

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13

Carboxylic acid → ester

Alcohol, H2SO4

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14

Ester → carboxylate and alcohol

NaOH

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15

Ester → carboxylic acid

dilute acid

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16

carboxylic acid→ acyl chloride

SOCl2

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17

acyl chloride → carboxylic acid

H2O

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18

Aldehyde → hydroxynitrile

NaCN, H+

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19

Acyl chloride → primary amide

NH3

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20

Acyl chloride → secondary amide

Primary amine

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21

benzene→ methylbenzene

CH3Cl, AlCl3

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22

benzene→ halobenzene

X2, halogen carrier

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23

benzene→ phenylethanone

CH3COCl, AlCl3

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24

benzene → nitrobenzene

HNO3, H2SO4

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25

nitrobenzene→ phenylamine

Sn, HCl → NaOH

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26

phenylethanone → 1-phenylethanol

NaBH4/ [H]

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27

phenylamine → 2,4,6 tribromoaminobenzene.

3Br2

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