AP Chem Unit 5: Kinetics

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What is required for two molecules to react once they collide?

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14 Terms

1

What is required for two molecules to react once they collide?

  • correct orientation

  • adequate activation energy (speed)

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2

What are the four factors to effect reaction rate?

  • concentration/pressure

  • temperature

  • surface area

  • catalyst

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3

What is the standard form of a rate law?

Rate =K[A]^x[B]^y

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4

if Z is the factor by which your concentration changes and Y is the factor by which your rate changes, what formula could be used to find the order?

Z^n=Y

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5

If the initial concentration is doubled, what change in the initial rate would reflect zero order?

zero order = no change in rate

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6

If the initial concentration is doubled, what change in the initial rate would reflect first order?

first order = doubled

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7

If the initial concentration is doubled, what change in the initial rate would reflect second order?

second order = quadrupled

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8

If the initial concentration is doubled, what change in the initial rate would reflect third order?

third order = octupled

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9

As the concentration of products increases, the value of K does what?

Increases, [products]/[reactants]

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10

As the concentration of reactants increases, the value of K does what?

Decreases, [products]/[reactants]

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11

What is the integrated rate law for a zero order reaction?

[A] vs time

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12

What is the integrated rate law for a first order reaction?

ln[A] vs time

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13

What is the integrated rate law for a second order reaction?

1/[A] vs time

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14

How do catalysts increase the rate of a reaction?

By providing an alternative mechanism with a lower activation energy

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