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28 Terms
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Molecular Mass/atom mass
relative masses of atoms and molecules
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Unified atomic mass unit
1u=1.6605x10^27kg
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Temperature
average kinetic energy of the particles within a substance
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thermometer
An instrument used to measure temperature
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Fahrenheit
°F=9/5°C+32
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Kelvin(absolute scale)
K=°C+273
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Celcius
°C=5/9(°F-32)
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Thermal Equilibrium+zeroth law of thermodynamics
Refers to the property of a thermodynamic system in which all parts of the system have attained a uniform temperature which is the same as that of the system's surroundings.
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linear expansion
L = L0 (1 + αΔ T )
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coefficient of expansion
the length change per unit of length/per degree of temperature
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volume expansion
ΔV = ßVΔT
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coefficient of volume expansion
The fractional change in volume per degree change in temperature.
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Boyle's Law
if temperature of a gas is held constant, the volume varies inversely with the pressure PV=constant
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Charles's Law
volume of a gas held at a constant pressure is directly proportional to the absolute temperature
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Gay-Lussac's Law
pressure exerted by gas held at a constant volume is directly proportional to the absolute pressure
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Ideal Gas Law
PV=nRT
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universal gas constant
R=8.314 J/molK
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Avogadro's Number
6.02x10^23
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Avogadro's hypothesis
Equal volumes of gases at the same temperature and pressure contain equal numbers of particles
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ideal gas law
PV=NkT
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Boltzmann's constant
k=R/NA=1.38 x 10^-23 K/K
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KE=3/2kT
the average translational kinetic energy of molecules in random motion in an ideal gas is directly proportional to the absolute temperature of the gas
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Root Mean Square Speed
square root of average of the squares of the magnitudes of the velocities of the molecules in a gas v rms=√(3kT/m)
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Critical Temperature
temperature where phase change occurs
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Triple Point
three phases can exist together in equilibrium
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Evaporation
liquid to gas
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Condensation
gas to liquid
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Boiling Point
temperature of liquid rises to the point at which vapor pressure inside bubbles equals or exceeds the external air pressure