CHEM: Acids, alkalis and bases

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What colour does litmus paper turn in acid/alkaline solutions?

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1

What colour does litmus paper turn in acid/alkaline solutions?

ACID: Red

ALKALI: Blue

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2

What range pH would be classified as strongly or weakly acidic?

Strongly acidic: 0-3

Weakly acidic: 4-6

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3

What range of pH would be classified as strongly or weakly alkaline?

Strongly alkaline: 11-14

Weakly alkaline: 8-10

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4

What colour does phenolphthalein turn in acidic/alkaline solutions?

ACID: Colourless

ALKALI: Pink

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5

What colour does methyl orange turn in acidic/alkaline solutions?

ACID: Red

ALKALI: Yellow

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6

What colour does universal indicator turn in acidic/alkaline solutions?

ACID: Red

NEUTRAL: Green

ALKALI: Purple

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7

What is an acid in aqueous solution?

A source of H+ ions

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8

What is an alkali in aqueous solution?

A source of OH- ions

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9

How would you carry out a titration?

  1. Use pipette to put 25 cm3 sodium hydroxide in conical flask and add indicator (must have sharp colour change)

  2. Place conical flask on white tile, tip of burette in flask

  3. Pour acid into burette using a funnel and take initial reading

  4. Perform rough titration by running the acid in quite quickly, swirling the flask

  5. Record end reading, make sure meniscus is at eye level

  6. Repeat with new sodium hydroxide

  7. Add acid one drop at a time near the end point

  8. Stop as soon as colour of the indicator in the sodium hydroxide changes

  9. Record final volume to nearest 0.05cm3

  10. Repeat until two concordant results (within 0.2 cm3 of each other) to increase accuracy

<ol><li><p>Use pipette to put 25 cm<sup>3</sup>&nbsp;sodium hydroxide in conical flask and add indicator (must have sharp colour change)</p></li><li><p>Place conical flask on white tile, tip of burette in flask</p></li><li><p>Pour acid into burette using a funnel and take initial reading</p></li><li><p>Perform rough titration by running the acid in quite quickly, swirling the flask</p></li><li><p>Record end reading, make sure meniscus is at eye level</p></li><li><p>Repeat with new sodium hydroxide</p></li><li><p>Add acid one drop at a time near the end point</p></li><li><p>Stop as soon as colour of the indicator in the sodium hydroxide changes</p></li><li><p>Record final volume to nearest 0.05cm<sup>3</sup></p></li><li><p>Repeat until two concordant results (within 0.2 cm<sup>3</sup>&nbsp;of each other) to increase accuracy</p></li></ol>
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10

Why must you constantly mix the flask when performing a titration?

To ensure everything reacts before more solution is added

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11

Why do you put the conical flask on a white tile in a titration?

To clearly identify when the colour change has occurred

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12

Why would you perform a titration?

To make a soluble salt. You can find out the exact volume of one solution it takes to neutralise an accurately measured known volume of another solution.

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13

How would you repeat a titration to produce a pure soluble salt?

Repeat without indicator and add the concordant value of the volume required to react with the solution

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14

HCl (aq) + NaOH (aq) → NaCl (aq) + H2O (l)

How would you make this an ionic equation?

H+ + OH- → H2O

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15

What happens in a neutralisation between acids and bases?

If the base is insoluble it cannot release OH- ions in solution. A proton is transferred from the acid (proton donor) to the base (proton acceptor.)

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16

Which salts are always soluble?

Sodium, potassium, ammonium salts and nitrates

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17

Are chlorides soluble?

Yes except for silver and lead (II) chlorides

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18

Are sulphates soluble?

Yes, except for barium, calcium and lead (II) sulphates

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19

Are carbonates soluble?

No, apart from the ones that are always soluble (Na, K, NH4+).

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20

What is an ammonium ion?

NH4+

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21

Are hydroxides soluble?

No, except the ones that are always soluble (Na, K, NH4+). Calcium hydroxide is slightly soluble.

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22

What is a precipitation reaction?

When two soluble salts are mixed to form an insoluble precipitate

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23

Acid + metal →

Acid + metal → Salt + hydrogen

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24

Acid + metal oxide →

Acid + metal oxide → Salt + water

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25

Acid + metal hydroxide →

Acid + metal hydroxide → Salt + water

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26

Acid + metal carbonate →

Acid + metal carbonate → Salt + water + carbon dioxide

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27

Examples of bases

Metal oxides, hydroxides and metal carbonates

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28

What is a precipitate?

An insoluble product of two solutions reacting

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29

How would you make an insoluble salt?

Precipitation reaction:

Mix together two separate aqueous solutions (one with required positive ion and one with negative ion)

Filter and keep precipitate

Rinse with distilled water

Leave to dry in a warm place

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30

How would you make a soluble salt (not Na, K or NH4+)?

Excess base:

  1. Acid in beaker, gently heat with tripod, gauze and Bunsen burner

  2. Add an excess of the insoluble base (metal, metal oxide, hydroxide, carbonate) - it is in excess when no more disappears (dissolves) upon stirring

  3. Filter off excess solid

  4. Transfer filtrate to evaporating basin, heat until left with a saturated solution

  5. Allow solution to cool and crystals to form

  6. Filter out crystals, rinse with a little distilled water (not too much as it is soluble)

  7. Dry crystals in warm place

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31

Why do crystals appear as the saturated solution cools in the excess base method?

If the solution is saturated while hot, less can dissolve as it cools so crystals start to form

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32

Why do we rinse the salt at the end?

To remove soluble impurities

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33

Why is the mixture filtered in the excess base method?

To remove the excess of the excess base

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34

Why shouldn’t you heat crystals to complete dryness?

The water of crystallisation would evaporate and the crystals would be anhydrous

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35

Why add an excess of the base?

To ensure that all of the acid has reacted to obtain pure crystals

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36

Why should you use indicator paper rather than aqueous indicator when preparing salts?

The indicator is an impurity

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37

Why is effervescence (fizzing) observed when a metal or metal carbonate reacts with an acid?

Metal + acid → Salt + hydrogen

Hydrogen is a gas so appears as bubbles

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38

Ammonia (NH3) + acid →

Ammonia (NH3) + acid → Ammonium salt (NH4)

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