Periodic Trends and Attraction

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Periodic trends and electron characteristics

10 Terms

1

coulombic attraction

force of attraction between oppositely charged particles (protons and electrons)

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2

coulombic potential

energy associated with coulombic attraction

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3

atomic radius

distance from the center of the nucleus of an atom to the edge of the electron cloud

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4

ionization energy

amount of energy required to remove the most loosely held electron from an atom — in the valence level (ionizing the atom into +1); opposite of coulombic

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5

electron affinity

the amount of energy released when an electron is gained by a neutral atom in the gaseous state to form a (-) ion

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6

electronegativity

ability of an atom to attract shared electrons away from another atom in a bond; how strongly an atom pulls on electrons from another atom while bonded

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7

effective nuclear charge

number of protons - number of valence electrons; larger number means a greater core charge and stronger attraction to electrons

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8

successive ionization

ionization energy increases for each electron removed from the electron cloud; dramatic increase for the electron following the final valence electron

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9

group 2 → group 13 ionization trend exception

(s2) → (s2p1)
the p sublevel is higher in energy and farther from the nucleus, which is greater than the attraction from the additional proton; decreases the coulombic attraction/potential and therefore the ionization energy

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10

group 15 → group 16 ionization trend exception

(p3 ↑ ↑ ↑) → (p4 ↑↓ ↑ ↑)
the paired electron spin level creates repulsion, which is greater than the attractive force from the additional proton; decreases the coulombic attraction/potential and therefore the ionization energy

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