Ch. 2 Water

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Last updated 7:08 AM on 2/5/26
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47 Terms

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Covalent bond

A bond formed by sharing electrons between atoms

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Nonpolar covalent bond

Electrons are shared equally between atoms

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Polar covalent bond

Electrons are shared unequally due to electronegativity differences

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Electronegativity

An atom’s attraction for shared electrons

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Oxygen and nitrogen

Which atoms are highly electronegative in biology?

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Bent shape + oxygen pulls electrons more strongly

Why is water polar?

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Dipole moment

Separation of partial charges in a molecule

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Hydrogen bonded to O, N, or F

What atoms form hydrogen bonds?

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Weak individually, strong collectively

Are hydrogen bonds strong or weak?

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Extensive hydrogen bonding

What causes water’s high boiling point?

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Hydrogen bonds hold molecules farther apart in a lattice

Why is ice less dense than liquid water?

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DNA, proteins, cellulose

What biological structures rely on hydrogen bonds?

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Hydrogen bonding between water molecules

Why does water have high cohesion?

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They form fewer hydrogen bonds

Why do other hydrides have lower boiling points than water?

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Bonds become more ordered and spaced

What happens to hydrogen bonding when water freezes?

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Hydrophobic effect

Nonpolar molecules avoid water and cluster together

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Water prefers hydrogen bonding with itself

Why don’t oil and water mix?

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Amphipathic molecule

Has hydrophobic and hydrophilic regions

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Micelle

Spherical cluster of amphipathic molecules in water

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Cell membranes and protein folding

What structures rely on the hydrophobic effect?

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Ionic and polar molecules

What types of molecules dissolve in water?

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Water surrounds and stabilizes ions (solvation)

Why do ionic compounds dissolve?

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Hydrogen bonding with water

Why do polar molecules dissolve?

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Nonpolar molecules

What types of molecules do NOT dissolve well?

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H2O ⇌ H+ + OH-

What reaction occurs in pure water?

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They are equal

What is true about [H+] and [OH-] in pure water?

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Acid

Increases hydrogen ion concentration

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Base

Decreases hydrogen ion concentration

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Strong fully dissociates; weak partially dissociates

Strong vs weak acid difference?

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[H⁺] > [OH⁻]

When is a solution acidic?

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[OH⁻] > [H⁺]

When is a solution basic?

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pH equation

pH = −log[H⁺]

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Hydrogen ion concentration

What does pH measure?

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7

What is a neutral pH?

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<7

What pH values are acidic?

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>7

What pH values are basic?

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10x

How much does acidity change per pH unit?

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pKa

-log(Ka), measure of acid strength

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Stronger acid

Lower pKa means what?

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Buffer

Weak acid + conjugate base that resists pH change

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When pH ≈ pKa

When is buffering strongest?

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±1 pH unit of pKa

Buffer effective range?

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Henderson–Hasselbalch equation

pH = pKa + log([A⁻]/[HA])

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pH increases

What happens if [A⁻] increases?

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Titration curve

Graph of pH vs added acid/base

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At the pKa region

Where is buffering strongest on a titration curve?

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Acid neutralized by base

What happens at equivalence point?

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