Chemistry Concepts Review

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Vocabulary flashcards covering key chemistry concepts including molecular geometry, hybridization, types of radiation, solubility rules, and more.

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34 Terms

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VSEPR Theory

A theory used to predict the molecular geometry of molecules based on the repulsion between electron pairs.

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109.5°

The bond angle associated with tetrahedral, trigonal pyramidal, and bent molecular geometries (sp³ hybridization).

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120°

The bond angle associated with trigonal planar and bentangular molecular geometries (sp² hybridization).

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180°

The bond angle associated with linear molecular geometry (sp hybridization).

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Microwave Radiation

Type of electromagnetic radiation that causes the rotation of molecules.

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Infrared Radiation

Type of electromagnetic radiation that causes the vibration of molecules.

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Ultraviolet/Visible Radiation

Type of electromagnetic radiation that causes electrons to transition between different energy levels.

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Solubility Rules for Compounds

Compounds containing Na+, K+, and NH4+ are always soluble in water; compounds containing NO3- are also always soluble in water.

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Bond Enthalpies Formula

ΔH = Σ Hbb - Σ H bF, which calculates the overall change in enthalpy during a reaction.

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Strong Acids

Acids that completely dissociate in water, including HCl, HBr, HI, HNO3, H2SO4, and HClO4.

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Strong Bases

Bases that completely dissociate in water, specifically Group 1 and 2 hydroxides such as LiOH, NaOH, KOH, Ca(OH)2, Sr(OH)2, and Ba(OH)2.

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Percent Error Formula

% error = (|calculated answer - correct answer| / correct answer) x 100.

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Exothermic Reaction (ΔH < 0)

A reaction that releases heat and has a negative change in enthalpy.

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Endothermic Reaction (ΔH > 0)

A reaction that absorbs heat and has a positive change in enthalpy.

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Thermodynamically Favored

A process or reaction that is spontaneous and has a negative Gibbs Free Energy change (ΔG < 0).

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Non-Thermodynamically Favored

A process or reaction that is not spontaneous and has a positive Gibbs Free Energy change (ΔG > 0).

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+ ΔH and - ΔS

Never favorable

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- ΔH and + ΔS

Always favorable

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+ ΔH and + ΔS

Favorable at HIGH temperatures

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- ΔH and - ΔS

Favorable at LOW temperatures

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CAT gets FAT

A metallic CAThode always increases in mass

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Direction electrons in a galvanic cell

From anode to cathode (A/C)

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Salt Bridge

Anions to anions, cations to cations

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Standard cell potential

E cell = E cathode — E anode

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Molar heat of solution

ΔH* = q / n

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Percent yield

Actual / theoretical x 100

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Percent composition

Mass / total mass x 100

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Nick the Camel…

ate Clam Supper in Phoenix with Brad

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Per____

One more O atom, most O atoms possible

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Hypo____

One less O than “ite,” least possibly

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More electrons

More polarizable

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Polarizability

Ease with which the electron cloud can be distorted (create dipole moment)

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Formal Charge

VE - NBE - B

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Total K eq with reaction steps

K eq1 x Keq2