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Eclipsed conformations
Higher energy (groups aligned).
θ = 0°
Eclipsed, highest energy): Methyl groups are directly aligned.
θ = 120°
(Eclipsed, high energy): Methyl aligned with hydrogen, less repulsion than at 0°.
θ = 180°
(Anti, lowest energy): Methyl groups are directly opposite each other, most stable.
θ = 60°
(Gauche, local minimum): Methyl groups are staggered but close.
240°
eclipsed
300°