7.3.1-2 - Addition & Condensation Polymerisation

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What is a polymer?

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8 Terms

1

What is a polymer?

A long chain molecule which is made by lots of smaller molecules joining together.

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2

How do molecules containing C=C bond form polymers?

  • C=C bonds open up and many smaller molecules (monomers) join together to form a chain (a polymer). No other products are made.

  • It’s called an “addition polymerization” reaction.

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3

Give three examples of addition polymers and their uses.

  • Polyethene - plastic bags.

  • (Poly)tetrafluoroethene (PTFE) - teflon surfaces, for use in non-stick kitchenware.

  • (Poly)chloroethene (polyvinylchloride, PVC) - water pipes.

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4

What is a repeating unit of a polymer?

  • It is a smallest structure which, upon numerous translations, yields the structure of the polymer.

  • In addition polymers: to draw it, take a monomer, change C=C to C-C and show additional single bonds extending away from these carbons.

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5

What is a condensation polymer?

A polymer made in condensation polymerization.

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6

How are condensation polymers made?

In this reaction, many molecules join together; the polymer is formed, but also a small molecule is released, e.g. H2O, HCl.

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7

What are the two main groups of condensation polymers? Name industrially relevant examples.

  • Polyesters, e.g. terylene.

  • Polyamides, e.g. Nylon.

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8

What is an amide bond?

  • Similar to the ester bond, with O replaced by N.

  • e.g. (C=O)-NH2.

  • Just like an ester, it contains the C=O group.

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