Dienes and Pericyclics
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8 Terms
Conjugated system
it is a system of connected p-orbitals with delocalized electrons in compounds with alternating single and double bonds
3 classes of dienes
Isolated, conjugated, and cummulated
Isolated diene
double bond separated by more than one single bond
Conjugated diene
double bonds separated by single bonds
Which diene is more stable
conjugated dienes are more stable than similar isolated dienes
Kinetic product
at low temperature, 1,2 product is formed faster
Thermodynamic product
at high temperature, 1,4 product is more stable because it predominates at equilibrium
What does it mean if a reaction is concerted?
this means that all electron reorganizations take place in a single step
Note 
Flashcards (152)