Reactions of Aromatics
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9 Terms
what are the conditions of nitration?
conc HNO3, H2SO4, 50C
what is the reaction that generates the nitronium ion electrophile?
HNO3 + 2H2SO4 —> NO2+ + 2HSO4- + H3O+
what are the conditions for the Friedel- crafts acylation reaction?
heat under reflux
what is a common halogen carrier and what does it do?
AlCl3 generates the E+ electrophile
what is the electrophile for the acylation reaction?
RC+=O
what is the Friedel-crafts alkylation reaction?
adding a carbon chain
what is the reaction where a carbocation electrophile is formed?
R- CH2 -Cl + AlCl3 —> R-CH2+ + AlCl4
what is the electrophile for the sulfonation of the ring reaction?
SO3
what are the conditions for a sulfonation reaction?
heat under reflux
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