A-level Chemistry: The Transition Metals Intro.

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27 Terms

1

What Are The d-block Elements?

The elements that sit at the middle of the periodic table.

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2

What Is A Transition Metal?

A metal/d-block element that can from at least one stable ion with an incomplete d-subshell.

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3

How Many Electrons Can The D-Subshell Hold?

Up to 10 electrons.

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4

Why Aren’t Zinc And Scandium Transition Metals?

Because they don’t form stable ions with an incomplete d-subshell.

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5

Why Do Electrons Fill Up Singly First Before Pairing Up When Considering Electron Configuration?

Because electrons repel each other.

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6

What Is The Electron Configuration Of Titanium (Ti)?

1s2, 2s2, 2p6, 3s2, 3p6, 3d2, 4s2.

OR

[Ar], 3d2, 4s2.

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7

What Is The Electron Configuration Of Chromium (Cr)?

1s2, 2s2, 2p6, 3s2, 3p6, 3d5, 4s1.

OR

[Ar], 3d5, 4s1.

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8

What Is The Electron Configuration For Copper (Cu)?

1s2, 2s2, 2p6, 3s2, 3p6, 3d10, 4s1.

OR

[Ar], 3d10, 4s1.

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9

Copper’s Short-Hand Electron Configuration Is [Ar] 3d10, 4s1. Why Is It Not [Ar] 3d9, 4s2?

Because one of the electrons from the 4s orbital moves into the 3d orbital in order to create a full, more stable, 3d sub-shell.

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10

Chromium’s (Short-Hand) Electron Configuration Is [Ar] 3d5, 4s1. Why Is It Not [Ar], 3d4, 4s2?

Because one of the electrons from the 4s orbital moves into the 3d orbital in order to create a half-full, more stable, 3d sub-shell.

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11

Scandium Forms A Stable Ion Of Sc³⁺. Why Is Scandium Not Considered A Transition Metal?

Transition metals are metals that form stable ions with incomplete 3d-subshells.

Though Sc has an incomplete d-subshell, its stable ion Sc³⁺

has an empty d-subshell.

Scandium is therefore not a transition metal.

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12

Zinc Forms A Stable Ion Of Zn²⁺. Why Is Zinc Not Considered A Transition Metal?

Transition metals are metals that form stable ions with incomplete 3d-subshells.

Both Zn and its stable ion Zn²⁺ have a full d-subshell.

Zinc is therefore not a transition metal.

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13

What Are The General Properties Of Transition Metals?

  1. They have variable oxidation states

  2. Form coloured ions in solution

  3. Are good catalysts

  4. They can form complex ions

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14

What Ions Does Vanadium (V) Form?

V²⁺

V³⁺

VO²⁺

VO2⁺

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15

What Ion(s) Does Manganate (Mn) Form?

Mn²⁺

MnO4⁻

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16

What Ion(s) Does Iron (Fe) Form?

Fe²⁺

Fe³⁺

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17

What Ion(s) Does Cobalt Form?

Co²⁺

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18

What Ion(s) Does Nickel (Ni) Form?

Ni²⁺

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19

What Ion(s) Does Copper (Cu) Form?

Cu²⁺

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20

What Ion(s) Does Chromium (Cr) Form?

Cr³⁺

Cr2O7²⁻

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21

What Colours Are Vanadium (V)’s Ions When Reacting In Aqueous Solution?

: Violet

V³⁺: Green

VO²⁺: Blue

VO2⁺: Yellow

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22

What Colours Are Chromium (Cr)’s Ion(s) In Aqueous Solution?

Cr³⁺: Violet

Cr2O7²⁻: Orange

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23

What Colours Are Manganese (Mn)’s Ion(s) In Aqueous Solution?

Mn²⁺: Very pale pink/Colourless

MnO4²⁻: Green

MnO4⁻: Purple

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24

What Colour Are Iron (Fe)’s Ion(s) In Aqueous Solution?

Fe²⁺: Pale green

Fe³⁺: Yellow

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25

What Colours Are Cobalt (Co)’s Ion(s) In Aqueous Solution?

Co²⁺: Pink

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26

What Colour Are Nickel (Ni)’s Ion(s) In Aqueous Solution?

Ni²⁺: Green

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27

What Colour Are Copper (Cu)’s Ion(s) In Aqueous Solution?

Cu²⁺: (Pale) blue

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