Part II. Multiple choice, continued (3 points each). Name:__________________ Please circle your answer. There is only one correct answer to each question. 52. A mixture of He and Ne at a total pressure of 0.95 atm is found to contain 0.32 mol of He and 0.56 mol of Ne. The partial pressure of Ne is __________ atm. A) 0.60 B) 1.5 C) 1.0 D) 0.35 53. Of the following gases, _____________ will have the greatest rate of effusion at a given temperature. A) NH3 B) CH4 C) Ar D) HCl 54. Which noble gas is expected to show the largest deviations from the ideal gas behavior? A) helium B) neon C) argon D) krypton 55. Together, liquids and solids constitute _______ phases of matter. A) the compressible B) the fluid C) the condensed D) the disordered 56. What is the predominant intermolecular force in liquid CBr4? A) dispersion B) dipole-dipole C) ion-dipole D) hydrogen bonds 57. Of the following substances, ____________ has the highest boiling point. A) H2O B) CO2 C) CH4 D) Kr 58. Of the following substances, ____________ has the lowest boiling point. A) Kr B) Ar C) Ne D) Xe 59. What is the predominant intermolecular force in liquid HBr? A) dispersion B) dipole-dipole C) ion-dipole D) hydrogen bonds 60. The total pressure of a mixture of O2 and N2 is 730 torr. The partial pressure of N2 is 0.78 atm. The partial pressure of O2 is A) 0.18 atm B) 0.22 atm C) 0.26 atm D) 0.78 atm

Part II. Multiple choice, continued (3 points each). Name:__________________ Please circle your answer. There is only one correct answer to each question. 43. The F-N-F bond angle in the NF3 molecule is slightly less than ___________. A) 90˚ B) 109.5 ˚ C) 120˚ D) 180˚ 44. The angles between sp2 orbitals are _____________. A) 90˚ B) 109.5˚ C) 120˚ D) 180˚ 45. The blending of one s atomic orbital and two p atomic orbitals produces __________. A) three sp hybrid orbitals B) three sp2 hybrid orbitals C) three sp3 hybrid orbitals D) two sp3 hybrid orbitals 46. The π bond in ethylene, CH2CH2, results from the overlap of ___________. A) sp3 hybrid orbitals B) s atomic orbitals C) sp2 hybrid orbitals D) p atomic orbitals 47. The amount of gas that occupies 60.82 L at 31˚ C and 367 mm Hg is _________ mol. A) 1.18 B) 0.850 C) 894 D) 11.6 48. The specific heat of lead is 0.13 J/g-K. How much heat (in J) is required to raise the temperature of 15 g of lead from 22 ˚C to 37 ˚C? A) 7.8 B) 1.9 C) 19 D) 29 49. Which one of the following is a weak acid? A) HNO3 B) HI C) HF D) HClO4 50. Which combination will produce a precipitate? A) NH4OH (aq) and HCl (aq) B) AgNO3 (aq) and Ca(C2H3O2)2 (aq) C) NaCl(aq) and HC2H3O2 (aq) D) NaOH (aq) and Fe(NO3)2 (aq) 51. The density of chlorine (Cl2) gas at 25 ˚C and 450 torr is _______ g/L. A) 20 B) 4.9 C) 1.7 D) 0.86

Multiple choice, continued (3 points each). Name:__________________ Please circle your answer. There is only one correct answer to each question. 36. How many different resonance structures can be drawn for the molecule SO3 without having to violate the octet rule on the sulfur atom? A) 5 B) 4 C) 3 D) 2 37. The central atom in _______ does not violate the octet rule. A) CF4 B) KrF2 C) SF4 D) XeF4 38. For a given arrangement of ions, the lattice energy increases as ionic radius _________ and as ionic charge __________. A) increases, increases B) decreases, decreases C) increases, decreases D) decreases, increases 39. Of the molecules below, only ________ is nonpolar. A) HCl B) NH3 C) SO2 D) CO2 40. Using the table of bond dissociation energies, ∆H for the reaction 2HCl (g) + F2 (g) à 2HF (g) + Cl2 (g) is __________ kJ. Bond D (kJ/mol) H – Cl 431 F – F 155 H – F 567 Cl – Cl 242 A) –359 B) -223 C) 359 D) 223 41. Considering its Lewis structure, the electron-domain geometry of oxygen in OF2 is ___________. A) trigonal planar B) trigonal bipyramidal C) octahedral D) tetrahedral 42. The electron-domain geometry and the molecular geometry of ammonia, NH3, are __________ and __________, respectively. A) tetrahedral, trigonal pyramidal B) tetrahedral, trigonal planar C) bent, bent D) trigonal planar, bent

Part II. Multiple choice, continued (3 points each). Name:__________________ Please circle your answer. There is only one correct answer to each question. 27. What volume (mL) of 0.135 M NaOH is required to neutralize 13.7 mL of 0.129 M HCl? A) 13.1 B) 0.24 C) 14.3 D) 6.55 28. All of the orbitals in a given electron shell have the same value of the ___________ quantum number. A) principal B) azimuthal C) magnetic D) spin 29. The places where the value of Y2 is zero are called ___________. A) orbitals B) nodes C) orbits D) wave functions 30. Of the following elements, which has the largest first ionization energy? A) B B) N C) P D) Si 31. Which equation correctly represents the second ionization of phosphorous? A) P+(g) + e- à P2+(g) B) P(g) à P+(g) + e- C) P+(g) à P2+(g) + e- D) P-(g) + e- à P2-(g) 32. Which of the following does not have eight valence electrons? A) Rb+ B) Ca+ C) Xe D) Br- 33. Of the atoms below, ____________ is the least electronegative. A) Cl B) Si C) F D) Rb 34. Of the bonds below, __________ is the least polar. A) Na - S B) P - S C) Na - Cl D) Si - Cl 35. In the Lewis structure of ClF, the formal charge on Cl is ______ and the formal charge on F is ________. A) –1, -1 B) 0, -1 C) 0, 0 D) +1, -1

Part II. Multiple choice, continued (3 points each). Name:__________________ Please circle your answer. There is only one correct answer to each question. 22. ∆E for a system that releases 12.4 J of heat and does 4.2 J of work on the surroundings is ____________ J. A) 16.6 B) 12.4 C) –8.2 D) –16.6 23. ∆H for an endothermic process is _________ while ∆H for an exothermic process is __________. A) zero, positive B) positive, negative C) negative, zero D) negative, positive 24. The value of ∆H˚ for the reaction below is –283 kJ. Calculate the heat (kJ) released to the surroundings when 12.0 g of CO reacts completely. CO (g) + O2 (g) à CO2 (g) A) 121 B) 660 C) 283 D) 212 25. Given the following reactions N2 (g) + 2O2 (g) à 2NO2 (g) ∆H = 66.4 kJ 2NO (g) + O2 (g) à 2NO2 (g) ∆H = -114.2 kJ the enthalpy of the reaction of nitrogen to produce nitric oxide N2 (g) + O2 (g) à 2NO (g) is __________ kJ. A) 180.6 B) –47.8 C) 47.8 D) –180.6 26. Given the data in the table below, ∆H˚ for the reaction 2CO (g) + O2 (g) à 2CO2 (g) is __________ kJ. Substance ∆Hf˚ (kJ/mol) CO (g) -110.5 CO2 (g) -393.5 CaCO3 (s) -1207.1 A) –677.0 B) 283.3 C) –283.0 D) –566.0