Electrolysis Concepts & Review (Youtube Playlist Included)

https://youtube.com/playlist?list=PLSH4WOwvkQzwLl-G5CGJZAIsofkp4wrc0

<<Video Includes: Oxidation numbers, oxidation-reduction, what is oxidized and reduced, galvanic (voltaic) cells, standard cell potential, voltage, E cell, electrolytic cell, drawing, Molten salt, Electrolysis of water, Gibbs Free Energy, potentials, standard hydrogen electrode, and a crash course on electrochemistry.<<

}}Videos provided by CrashCourse, Mike Sugiyama Jones, The Organic Chemistry Tutor, Tony Hussey, Conquer Chemistry, Richard Thornley, Rachel Johnson, Professor Dave Explains.}}

Ox An Red Cat

Oxidation at the Anode

Reduction at the Cathode

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S.H.E. is standard hydrogen electrode (2H+ + 2e- → H2)

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Gibbs free energy = - n * F * E Cell

  • n = moles of e-
  • F = 96485C / mole e-
  • E Cell = cell potential

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Galvanic cellElectrolytic cell
SpontaneousNon spontaneous
G < 0G > 0
E Cell > 0E Cell < 0
Thermodynamically favorableThermodynamically unfavorable
Positive ions leave the anode (-) and electrons travel to the cathode (+).Positive ions flow to cathode (-).
Anions flow to anode.External power source
Chemical energy → electrical energyElectrical energy → chemical energy

Electrons always flow anode to cathode.

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Charge = A*S

  • A = Current
  • S = Time in seconds

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The Electrolysis of water

2H2O → 2H2 + O2

H+ goes to cathode to be reduced

Cathode: 2H+ + 2e- → H2

Anode: 2O2 → 2e- + O2

H2SO4 is added as a catalyst

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Example of factor labeling:

# Minutes60 Seconds# AmpsC1 mole e-# mole elementmolar mass g
1 MinuteA * S96485 C# mole e-1 mole

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