Steric Strain Values

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Last updated 10:33 PM on 9/11/26
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11 Terms

1
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-CH3

methyl; 1.70

2
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-CH2CH3

ethyl; 1.75

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-CH(CH3)2

isopropyl; 2.15

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-C(CH3)3

tert-butyl; 4.9

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<p>benzene/arene</p>

benzene/arene

3.0

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-C≡C-H

alkyne; 0.46

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-C≡N

nitrile; 0.21

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-OH

alcohol; 0.87

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-OCH3

methoxy; 0.67

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-SH

thiol; 1.20

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Trend for Halogens (F, Cl, Br, I)

F < Cl < Br < I; steric strain increases as the molecules gain size