Thermochemisrty

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13 Terms

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Exothermic

Give out heat

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Endothermic

Take in heat

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Heat of Reaction

The heat change that takes place when a chemical reaction proceeds according to its balanced equation.

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Heat of Combustion

The heat change that takes place when 1 mole of a substance is completely burned in excess O2.

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Heat of Combustion is measured by…….

Bomb calorimeter

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Kilogram Calorific Value

This is the heat energy produced when 1kg of a fuel is burned in O2. (We use this number to compare the efficiency of fuels)

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Bond Energies

Is the difference between the energy required to break all old bonds and the energy required to make all new bonds.

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What happens Bond Energies?

Energy is needed to break bonds (reactants). Energy is released when bonds are made (products).

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Heat of Neutralisation

The heat change that takes place when 1 mole of H+ ions and 1 mole of OH- ions react together

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E = mcθ is used to calculate the ΔH. What do they stand for.

E=energy, m=mass of water in kg, c=4200J/kg/K, θ=temperature rise

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C = 4200J/kg/K is called the specific heat capacity of water

It is the energy required to raise 1kg of water through 1°K

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Heat of Formation

It is the heat change that takes place when 1 mole of a substance is formed from its elements.

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Hess’s Law

The heat change for a given reaction was dependant only on the initial and final states of the system and was independent of the pathway followed