A substance that cannot be broken down into other substances by chemical reactions
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compound
a substance consisting of two or more different/same elements combined in a fixed ratio
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essential elements
elements needed to survive and reproduce(20-25%)
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CHON
96% of living matter
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trace elements
required by an organism in very small quantities
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atomic number
the number of protons in the nucleus(unique to each)
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atomic mass
number of protons and neutrons in the nucleus (averaged over all isotopes)
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isotopes
same number of protons and different number of nuetrons
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radioactive isotopes
nucleus decays spontaneously, giving off particles and energy
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group
elements in the same vertical column; same number of valence electrons
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period
elements in the same horizontal row; same total number of electron shells
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bohr model
shows electrons orbiting the nucleus of an atom
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1st shell
holds 2 electrons
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2nd shell
holds 8 electrons
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3rd shell
holds up to 18 electrons(happy with 8)
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lewis dot model
Simplified Bohr diagrams; does not show energy levels; only shows electrons in the VALENCE SHELL (outermost shell); electrons are placed around the element symbol
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chemical bonds
attraction between two atoms, resulting from the sharing or transferring of valence electrons
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octet rule
elements will gain, lose, or share electrons to complete their valence shell and become stable(like noble gases)
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electronegativity
a measure of an atom's ability to attract electrons to itself
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covalent bonds
when two or more atoms share electrons(usually between two nonmetals)
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single bond
one pair of shared electrons
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double bond
two pairs of shared electrons
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triple bond
three pairs of shared electrons
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nonpolar covalent bond
electrons are shared equally between two atoms
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polar covalent bond
electrons are NOT shared equally between two atoms; determine by electronegativity of atoms
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ionic bonds
the attraction between oppositely charges atoms(ions); usually between metal and nonmetal; metal transfers electrons to nonmetal
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cation
positively charged ion(metal)
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anion
negatively charged ion(nonmetal)
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hydrogen bonds
the partially positive hydrogen atom in one polar covalent molecule will be attracted to an electronegative atom in another polar covalent molecule
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FON
most electronegative elements
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intermolecular bond
bond that forms between molecules
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water
most abundant molecule in living organisms. only substance on Earth that naturally occurs in all 3 physical states of matter
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polarity (property of water)
unequal sharing of the electrons make water a polar molecule. since oxygen has a higher electronegativity than hydrogen
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cohesion (property of water)
attraction of molecules for other molecules of the same kind. responsible for surface tension. allows for the transport of h2o and nutrients against gravity in plants
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surface tension
property allowing liquid to resist external force
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adhesion (property of water)
the clinging of one molecule to a different molecule. occurs due to the polarity of h2o. in plants this allows water to cling to the cell walls to resist the downward pull of gravity
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capillary action (property of water)
the upward movement of water due to the forces of cohesion, adhesion, and surface tension. occurs when adhesion is GREATER than cohesion. important for transport of water and nutrients in plants
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high specific heat (temp control-property of water)
h2o resists changes in temperature by hydrogen bonds. heat must be absorbed to break hydrogen bonds, but heat is released when hydrogen bonds form
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importance of high specific heat
moderates air temperature, stabilizes ocean temperature, organisms can resist changes in their own internal temperature
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evaporative cooling (temp control-property of water)
water has a high heat of vaporization. molecules with the highest kinetic energy leave as gas
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Importance of evaporative cooling
Moderates earths climate, stabilizes temperature in lakes and ponds, prevents terrestrial organisms from overheating, and prevents leaves from becoming too warm in the sun
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density (property of water)
floating ice. as water solidifies it expands and becomes less dense. this occurs due to the hydrogen bonds, when cooled h2o molecules move too slowly to break the bonds, and hydrogen bonds cause water molecules to form a crystalline structure
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solvent (property of water)
dissolving agent in a solution
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type of solvent water is
versatile. its polar molecules are attracted to ions and other polar molecules it can form hydrogen bonds with. (example: water can interact with sugars or proteins containing many oxygen and hydrogen. water will form hydrogen bonds with the sugar or protein to dissolve it)
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solution
A homogeneous mixture of two or more substances
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solute
A substance that is dissolved in a solution.
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ionic compounds
compounds composed of cations and anions. the partially negative oxygen in water will interact with a positive atom. the partially positive hydrogen in water will interact with a negative atom. dissolves ions
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evaporation
liquid to gas (endothermic)
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condensation
gas to liquid (exothermic)
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depostition
gas to solid (exothermic)
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sublimation
solid to gas (endothermic)
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freezing
liquid to solid (exothermic)
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melting
solid to liquid (endothermic)
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transpiration
evaporation from the surface of plants
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4*C
water is most dense
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metabolism
All of the chemical reactions that occur within an organism
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metabolic pathways
series of chemical reactions that either build complex molecules or break down complex molecules. controlled by enzymes
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catabolic pathways
pathways that release energy by breaking down complex molecules into simpler compounds
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anabolic pathways
pathways that consume energy to build complicated molecules from simpler ones
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energy
the ability to do work
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kinetic energy
energy associated with motion
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thermal energy
type of kinetic energy. associated with the movement of atoms or molecules
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potential energy
stored energy
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chemical energy
potential energy available for release in a chemical reaction
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thermodynamics
The study of energy transformations that occur in a collection of matter. the laws apply to the universe as a whole
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1st law of thermodynamics
Energy cannot be created or destroyed. energy can be transferred or transformed
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2nd law of thermodynamics
energy transformation increases the entropy (disorder) of the universe. during energy transfers or transformations, some energy is unusable and often lost as heat
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free energy
energy available to do work. used to determine the likelihood of reactions in organisms, or if the reactions are energetically favorable
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free energy change of reactions
determine whether or not the reaction occurs spontaneously. causes an increase in entropy and is moving towards a chemical equilibrium
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exergonic reaction
reactions that release energy. example: cellular respiration (reaction is spontaneous). drive the formation of ATP
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endergonic reaction
reactions that absorb energy. example: photosynthesis (reaction is not spontaneous, absorb free energy). driven by hydrolysis of ATPorg
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Disequilibrium
if a cell reaches equilibrium it is "dead" therefore in a cell there is always this
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coupling
The extent to which subsystems depend on each other.
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mechanical (type of work cells perform)
movement (beating cilia, movement of chromosomes, contraction of muscle cells)
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transport (type of work cells perform)
pumping substances across membranes against spontaneous movement
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chemical (type of work cells perform)
synthesis of molecules (building polymers from monomers)
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ATP
(adenosine triphosphate) molecule that organisms use as a source of energy to perform work. couples exergonic reactions to endergonic reactions to power cellular work. organisms obtain energy by breaking the bond between the 2nd and 3rd phosphate in a hydrolysis reaction
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Phosphorylation
the released phosphate moves to another molecule to give energy
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Hydrolysis of ATP
releases energy and breaks off 3rd phosphate to create ADP
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organic chemistry
branch of science dealing with the element carbon and its many properties
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organic molecules
carbohydrates, lipids, proteins, nucleic acids
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carbon
tetravalent (4 valence electrons). can bone wit 4 other molecules allowing it to act like an intersection in the building of an organic molecule
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inorganic compounds
no carbon-hydrogen bonds
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itself, hydrogen, oxygen, nitrogen
common bonding partners of carbon
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alkanes
single bonded hydrocarbons. have most hydrogen. saturated. end in -ane
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alkenes
double bonded hydrocarbons. unsaturated. end in -ene
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alkynes
triple bonded between carbons. unsaturated
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hydrocarbons
molecules containing only carbon and hydrogen. use as fuel because of he huge amount of energy stored in these C-H bonds. non-polar and hydrophobic