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matter
anything that takes up space and has mass
element
A substance that cannot be broken down into other substances by chemical reactions
compound
a substance consisting of two or more different/same elements combined in a fixed ratio
essential elements
elements needed to survive and reproduce(20-25%)
CHON
96% of living matter
trace elements
required by an organism in very small quantities
atomic number
the number of protons in the nucleus(unique to each)
atomic mass
number of protons and neutrons in the nucleus (averaged over all isotopes)
isotopes
same number of protons and different number of nuetrons
radioactive isotopes
nucleus decays spontaneously, giving off particles and energy
group
elements in the same vertical column; same number of valence electrons
period
elements in the same horizontal row; same total number of electron shells
bohr model
shows electrons orbiting the nucleus of an atom
1st shell
holds 2 electrons
2nd shell
holds 8 electrons
3rd shell
holds up to 18 electrons(happy with 8)
lewis dot model
Simplified Bohr diagrams; does not show energy levels; only shows electrons in the VALENCE SHELL (outermost shell); electrons are placed around the element symbol
chemical bonds
attraction between two atoms, resulting from the sharing or transferring of valence electrons
octet rule
elements will gain, lose, or share electrons to complete their valence shell and become stable(like noble gases)
electronegativity
a measure of an atom's ability to attract electrons to itself
covalent bonds
when two or more atoms share electrons(usually between two nonmetals)
single bond
one pair of shared electrons
double bond
two pairs of shared electrons
triple bond
three pairs of shared electrons
nonpolar covalent bond
electrons are shared equally between two atoms
polar covalent bond
electrons are NOT shared equally between two atoms; determine by electronegativity of atoms
ionic bonds
the attraction between oppositely charges atoms(ions); usually between metal and nonmetal; metal transfers electrons to nonmetal
cation
positively charged ion(metal)
anion
negatively charged ion(nonmetal)
hydrogen bonds
the partially positive hydrogen atom in one polar covalent molecule will be attracted to an electronegative atom in another polar covalent molecule
FON
most electronegative elements
intermolecular bond
bond that forms between molecules
water
most abundant molecule in living organisms. only substance on Earth that naturally occurs in all 3 physical states of matter
polarity (property of water)
unequal sharing of the electrons make water a polar molecule. since oxygen has a higher electronegativity than hydrogen
cohesion (property of water)
attraction of molecules for other molecules of the same kind. responsible for surface tension. allows for the transport of h2o and nutrients against gravity in plants
surface tension
property allowing liquid to resist external force
adhesion (property of water)
the clinging of one molecule to a different molecule. occurs due to the polarity of h2o. in plants this allows water to cling to the cell walls to resist the downward pull of gravity
capillary action (property of water)
the upward movement of water due to the forces of cohesion, adhesion, and surface tension. occurs when adhesion is GREATER than cohesion. important for transport of water and nutrients in plants
high specific heat (temp control-property of water)
h2o resists changes in temperature by hydrogen bonds. heat must be absorbed to break hydrogen bonds, but heat is released when hydrogen bonds form
importance of high specific heat
moderates air temperature, stabilizes ocean temperature, organisms can resist changes in their own internal temperature
evaporative cooling (temp control-property of water)
water has a high heat of vaporization. molecules with the highest kinetic energy leave as gas
Importance of evaporative cooling
Moderates earths climate, stabilizes temperature in lakes and ponds, prevents terrestrial organisms from overheating, and prevents leaves from becoming too warm in the sun
density (property of water)
floating ice. as water solidifies it expands and becomes less dense. this occurs due to the hydrogen bonds, when cooled h2o molecules move too slowly to break the bonds, and hydrogen bonds cause water molecules to form a crystalline structure
solvent (property of water)
dissolving agent in a solution
type of solvent water is
versatile. its polar molecules are attracted to ions and other polar molecules it can form hydrogen bonds with. (example: water can interact with sugars or proteins containing many oxygen and hydrogen. water will form hydrogen bonds with the sugar or protein to dissolve it)
solution
A homogeneous mixture of two or more substances
solute
A substance that is dissolved in a solution.
ionic compounds
compounds composed of cations and anions. the partially negative oxygen in water will interact with a positive atom. the partially positive hydrogen in water will interact with a negative atom. dissolves ions
evaporation
liquid to gas (endothermic)
condensation
gas to liquid (exothermic)
depostition
gas to solid (exothermic)
sublimation
solid to gas (endothermic)
freezing
liquid to solid (exothermic)
melting
solid to liquid (endothermic)
transpiration
evaporation from the surface of plants
4*C
water is most dense
metabolism
All of the chemical reactions that occur within an organism
metabolic pathways
series of chemical reactions that either build complex molecules or break down complex molecules. controlled by enzymes
catabolic pathways
pathways that release energy by breaking down complex molecules into simpler compounds
anabolic pathways
pathways that consume energy to build complicated molecules from simpler ones
energy
the ability to do work
kinetic energy
energy associated with motion
thermal energy
type of kinetic energy. associated with the movement of atoms or molecules
potential energy
stored energy
chemical energy
potential energy available for release in a chemical reaction
thermodynamics
The study of energy transformations that occur in a collection of matter. the laws apply to the universe as a whole
1st law of thermodynamics
Energy cannot be created or destroyed. energy can be transferred or transformed
2nd law of thermodynamics
energy transformation increases the entropy (disorder) of the universe. during energy transfers or transformations, some energy is unusable and often lost as heat
free energy
energy available to do work. used to determine the likelihood of reactions in organisms, or if the reactions are energetically favorable
free energy change of reactions
determine whether or not the reaction occurs spontaneously. causes an increase in entropy and is moving towards a chemical equilibrium
exergonic reaction
reactions that release energy. example: cellular respiration (reaction is spontaneous). drive the formation of ATP
endergonic reaction
reactions that absorb energy. example: photosynthesis (reaction is not spontaneous, absorb free energy). driven by hydrolysis of ATPorg
Disequilibrium
if a cell reaches equilibrium it is "dead" therefore in a cell there is always this
coupling
The extent to which subsystems depend on each other.
mechanical (type of work cells perform)
movement (beating cilia, movement of chromosomes, contraction of muscle cells)
transport (type of work cells perform)
pumping substances across membranes against spontaneous movement
chemical (type of work cells perform)
synthesis of molecules (building polymers from monomers)
ATP
(adenosine triphosphate) molecule that organisms use as a source of energy to perform work. couples exergonic reactions to endergonic reactions to power cellular work. organisms obtain energy by breaking the bond between the 2nd and 3rd phosphate in a hydrolysis reaction
Phosphorylation
the released phosphate moves to another molecule to give energy
Hydrolysis of ATP
releases energy and breaks off 3rd phosphate to create ADP
organic chemistry
branch of science dealing with the element carbon and its many properties
organic molecules
carbohydrates, lipids, proteins, nucleic acids
carbon
tetravalent (4 valence electrons). can bone wit 4 other molecules allowing it to act like an intersection in the building of an organic molecule
inorganic compounds
no carbon-hydrogen bonds
itself, hydrogen, oxygen, nitrogen
common bonding partners of carbon
alkanes
single bonded hydrocarbons. have most hydrogen. saturated. end in -ane
alkenes
double bonded hydrocarbons. unsaturated. end in -ene
alkynes
triple bonded between carbons. unsaturated
hydrocarbons
molecules containing only carbon and hydrogen. use as fuel because of he huge amount of energy stored in these C-H bonds. non-polar and hydrophobic
Type of bond carbon forms
covalent
meth-
1 carbon
eth-
2 carbons
prop-
3 carbons
but-
4 carbons
pent-
5 carbons
hex-
6 carbons
hept-
7 carbons
oct-
8 carbons
non-
9 carbons
dec-
10 carbons