AQA A level Chem 3.08 Aldehydes and Ketones

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Aqueous NaBH4 reduces aldehydes but does not reduce alkenes.

Explain why NaBH4 reduces 2-methylbutanal but has no reaction with 2-methylbut-1-ene (2)

H- ion is attracted to the first carbonyl /Cs+ (1)

H- ion is repelled by the electron rich C=C (1)

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Acrylic fibres are used as a substitute for wool. Acrylics are copolymers of acrylonitrile with other compounds.

Acrylonitrile is the common name for the following compound.

H2C=CH-C≡N

Acrylonitrile can be formed from propene

Write an equation for the reaction for the reaction of propene with ammonia and oxygen to form acrylonitrile and one other product (1)

H2C=CH-C≡N + NH3 + 3/2O2 → CH2=CH-C≡N + 3H2O (1)

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