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46 Terms

1
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Toluene

2
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Phenol

3
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Aniline

4
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Acetophenone

5
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Benzaldehyde

6
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Benzoic Acid

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ortho-Xylene

8
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Stryrene

9
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Fluorination

10
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Bromination

11
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Chlorination

12
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Iodination

13
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Nitration

14
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Sulfonation

15
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Friedel-Crafts Alkylation

16
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Friedel Crafts Acylation

17
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Reduction of aromatic nitro group

18
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Nucleophilic Aromatic substitution by addition to activated halides

Works with HSO3 group as well instead of cl

19
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Nuc Aro Sub by form of benzene intermed

20
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Oxidation of alkylbenzene side chain

21
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Benzylic bromination of alkylbenzene

22
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Catalytic hydrogenation of aromatic ring

23
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Reduction of aryl alkyl ketones

24
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Reduction aldehyde

25
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Reduction Ketone

26
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Reduction Ester

27
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Reduction Carbox Acid

28
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Grinyard Fromeldehyde

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Grinyard Aldehyde

30
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Grinyard Ketone

31
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Grinyard Ester

32
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Dehydration

33
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Dehydratin secondary and tertiary

34
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Oxidation primary alc

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36
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Secondary alc

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Carbox for primary

38
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Phenol to anisole (to protect oh for friedel crafts)

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Deprotection of Anisole (Benzene - o - CH3) to form Phenol

BBr3 or HBr/Heat

40
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Make Phenol from Aniline

Aniline starter

  1. NaNO2, HCl in H2O

  2. H2O + heat

41
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42
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NH2 —> ClCOCH3 + Pyridine

H3O+, H2O, Heat

Stabilize NH2

Remove protecting group

43
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PCC (mild reducing agent)

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PDC (mild ox agent)

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Protect OH then deprotect

TMS in Et2N

Remove with acid (3M with heat) in water

46
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Remove HSO3

Dilute H2SO4 and heat