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amide (-CONH2) and carboxylic acid (-COOH)
#1 Most polar due to strong hydrogen bonding (both donating and accepting) and high dipole moments
Alcohol (–OH)
#2 Highly polar with strong hydrogen bonding via the hydroxyl group.
Amine (–NH₂)
#3 Polar and capable of hydrogen bonding
Ketone / Aldehyde (C=O)
#4 Polar carbonyl group that accepts hydrogen bonds but cannot donate them.
Ester (–COOR)
#5 Moderately polar, less polar than ketones
Ether (–O–)
#6 Weakly polar due to a single C–O bond with steric hindrance
Alkane / Alkyl Halide (–H, –R)
#7 Nonpolar or least polar, relying only on weak dispersion forces