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How many electrons do group one atoms have in their outer shell?
1
Properties of group 1 metals
fairly dense, malleable, can float on water
How is a positive ion formed?
It is formed when a metal atom loses electrons
How is a negative ion formed?
It is formed when a non-metal ion gains electrons
Ion
An atom with a positive or negative charge
Cations
positively charged ions
Anions
negatively charged ions
Ionic bonding
When positive ions and negative ions are strongly attracted to each other by electrostatic attraction
How should you refer to separate particles in ionic bonds?
ions
How should you refer to the compound in ionic bonding?
compound
What is the overall charge on any ionic compound?
0
Properties of ionic compounds
high melting and boiling points, are electrical conductors when liquid or aqueous
Giant Lattice Structure
When millions of ions are packed together in a regular cubic arrangement, joined by ionic bonds. There are strong electrostatic forces of attraction in giant lattice structures.
Why can ionic compounds carry a charge when liquid or aqueous?
Because the ions are free to move and carry a charge
Evaporation
When particles from the surface of a liquid turn into a gas. It can happen at any temperature between the melting and boiling point of a liquid.
Boiling
When all the particles in a liquid gain sufficient energy to turn into a gas. Can only occur at the boiling point of a liquid
What are the forces like between particles in a solid?
Strong
What is the arrangement of particles in a solid like?
Particles are in a fixed and regular arrangement.
How much energy do particles in a solid have?
Little (vibrate about fixed positions)
What is the arrangement of particles like in a liquid?
Particles are close and can move past each other. They are in an irregular arrangement.
What is the arrangement of particles like in a liquid?
Particles are close and can move past each other. They are in an irregular arrangement.
What is the arrangement of particles like in a liquid?
Particles are close and can move past each other. They are in an irregular arrangement.
How much energy do particles in a solid have?
More energy than solids (move at low speeds)
What are the forces of attraction in a gas like?
Weak
How are particles arranged in a solid?
Randomly. The particles are not touching and move freely
How much energy do particles in a gas have?
Particles have more energy than solids and liquids.
Gas to liquid
Condensing
Liquid to Solid
Freezing
Solid to Liquid
Melting
Liquid to Gas
Boiling/Evaporation
Gas to Solid
Deposition
Solid to Gas
Sublimation
Covalent Bonding
When non-metal atoms share electron pairs to obtain full outer shells
How should you refer to separate particles in covalent bonds?
atoms
How should you refer to a compound in covalent bonding?
molecule
What is the boiling point of a simple covalent molecule like?
Low
What are the bonds like within covalent molecules?
strong
What are the bonds like within covalent molecules?
strong
What are the melting and boiling points like in giant covalent structures?
Very high
In diamond structures, how many covalent bonds does each carbon atom form?
4
What are the covalent bonds in diamond like?
Strong, and therefore require a lot of energy to break
Properties of Diamond
High melting and boiling points, hard, very strong
In Graphite, how many covalent bonds does each carbon atom form?
3
After the carbon atoms have formed three covalent bonds in graphite, what does this leave?
A delocalised electron.
What can delocalised electrons do?
They can move between the layers and carry a charge through the structure.
What are the hexagonal rings of atoms in graphite called?
Graphene
What are layers of graphene held together with and what is the significance of this?
They are held together by weak intermolecular forces, which allow the layers to slide past one another
What molecules is silicon dioxide made of?
silicon and oxygen
How many oxygen atoms does each silicon atom bond to?
2
Why does graphene conduct electricity?
Because it only forms three covalent bonds, there is one delocalised electron which can move between the layers and carry a charge between the structure
What happens to reactivity as you descend group 7?
decreases
Why does reactivity decrease as you descend group 7?
Because the outer shell gets progressively further from the nucleus.
What type of reactions are halogen displacement reactions?
REDOX
What are the halogens?
group 7, primarily bromine, iodine, fluorine and chlorine
What colour is fluorine?
Yellow
What colour is chlorine?
Green
What colour is bromine?
Orange
What colour is Iodine?
Brown
Metallic Bonding
The strong electrostatic attraction between positive metal ions and a “sea” of shared, delocalised electrons, forming a giant, regular lattice structure.
Why are metals good conductors of heat and electricity?
Because delocalised electrons carry electrical charges and thermal energy through the whole structure.
Why do metals have high melting and boiling points?
Due to the strong electrostatic attraction between the positive metal ions and delocalised electrons, which require a lot of force to overcome.
Why are metals malleable?
Because the particles are arranged in neat rows which can slide over one another.
Advantages of dot and cross diagrams
Gives ratio of atoms in the molecule
Shows the type of single bond formed
Advantages of displayed diagrams
gives the ratio of atoms in the molecule
shows the type of single bond formed
Advantages of 3D models
shows a 3D arrangement of atoms in space
Shows the relative size of atoms in the molecule
shows the relative bond angles
Disadvantages of dot and cross diagrams
only a 2D representation
doesn’t show relative sizes of atoms
disadvantages of displayed diagram
only a 2D representation
doesn’t show relative sizes of atoms in the molecule
disadvantages of 3D model
doesn’t show the atoms in the molecule
doesn’t show the type of single bond formed
Fullerenes
Hollow carbon structures usually shaped like empty tubes or balls.
What are fullerenes mainly made up of?
hexagonal rings of carbon atoms
What can fullerenes be used for?
drug delivery, catalysts, lubricants
What was the first fullerene to be discovered?
Buckminster fullerene
Alloys
An alloy is a mixture of two or more elements, where at least one element is a metal
Why are alloys stronger and harder than most metals?
Because the different sizes of metal atoms disrupt the neat, layered structure, meaning the layers can no longer slide over one another
What are steels?
Alloys of iron
Nanoparticles
very small particles
Properties of nanoparticles
high length to diameter ratio, high tensile strength, high melting and boiling points, conductors electricity and thermal energy
How many atoms do nanoparticles contain?
a few hundred
How large are nanoparticles?
1-100 nanometres
What is the size of one atom?
0.1-0.5 nanometres
What is a nanoparticle’s surface area to volume ratio like?
high
μm to nm
x1000
mm to μm
x1000
Equation for area
Area = length x width
Equation for Surface Area
surface area = area x 6
Equation for volume
volume = length x width x height
Why are nanoparticles good catalysts?
High SA:V ratio allows more collisions to occur on the surface of a catalyst.
Why are nanoparticles good for use in cosmetics?
Small particles provide better sunscreen protection
Why are nanoparticles good for use in Nanomedicine?
fullerenes are easily absorbed by the body, so are ideal for drug delivery
Why are nanoparticles good for use as lubricants?
Fullerenes can be used in artificial joints or gears to keep them smooth.
Why are nanoparticles good in electrical circuits?
Nanotubes (graphite) can conduct electricity and so are used in computer chips
What can happen if nanoparticles build up in cells?
Lung inflammation, as nanoparticles used in medicine do not break down easily.
Mass Number
Number of protons + Number of neutrons
Atomic Number
Number of protons (or electrons)
Isotopes
Atoms of the same element that contain the same number of protons but different numbers of neutrons.
Relative Atomic Mass (Ar)
The average mass of an atom of an element, compared to 1/12th of the mass of an atom of carbon-12
Relative Formula Mass (Mr)
The sum of the relative masses of atoms in a compound.
Unit for Mr
g mol^-1
How is the percentage of an element in a compound calculated?
By dividing the mass of the element in question by the relative formula mass of the compound and then multiplying the value by one hundred
What is Avogadro’s Number?
6.02 ×10²³