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Alkali Metals
Valence electron of 1
Alkali Metals
Reacts with oxygen to form oxides
Alkali Metals
Reacts vigorously with water to form H2 and metallic hydroxide
Alkali Metals
Very reactive and do not occur free in nature
Alkali Metals
Li, Na, K, Rb, Cs, Fr
Lithium
produces crimson flame/carmine-red flame when added to HCl for flame test
Lithium Carbonate Precipitate
2Li + Na2CO3
Lithium Carbonate
white precipitate soluble in NH4Cl
No Precipitate
Li + SO42-
Sodium
produces persistent golden yellow flame with HCl in flame test
No precipitate
Na + K2CO3 (differentiates Sodium from Lithium)
Sodium Dihydrogen Pyroantimonate (Na2H2Sb2O7)
white complex precipitate formed by Sodium + Potassium Pyroantimonate
Potassium
produces a violet/lilac flame with HCl in flame test which only becomes visible when viewed through cobalt glass as the flame turns crimson in color
Lithium (Li+)
CNS (Central Nervous System) Depressant and Diuretic
Lithium Carbonate (Li2CO3)
Used in treating manic-depressive disorders
Sodium (Na+)
Most abundant salt in weakly acidic drugs and the most abundant extracellular cation
Potassium (K+)
most abundant intracellular cation
Alkaline Earth Metals
has a valence electron of 2
Alkaline Earth Metals
Be, Mg, Ca, Sr, Ba, Ra
Alkaline Earth Metals
attacked by atmospheric oxygen (execept Beryllium)
Alkaline Earth Metals
Reacts with water to form H2 and alkaline solution (except Beryllium and Magnesium)
Alkaline Earth Metals
not as reactive and soluble as GroupIA
Calcium > Strontium > Barium > Radium
solubility trend for alkaline earth metals except for hydroxides
Calcium < Strontium < Barium < Radium
solubility trend of hydroxides of alkaline earth metals
Calcium
forms a yellowish-red/brick red flame when reacted with HCl for a flame test
Barium
forms a yellowish-green flame when added with HCl for flame test
Berilium
the is and its salts are very toxic
Magnesium
used as an anti-convulsant and for vasodilation
Calcium
most abundant mineral in the body
Strontium
used as desensitizing agent in toothpastes (sensodyne)
Barium (BaSO4)
used as an xray contrast medium but only drank so that it doesn’t get distributed through the entire body
Radium
radioactive
Boron Family
has an oxidation state of 3+
GroupIIIA (Boron Family)
Tends to form covalent bonds greater than Groups IA and IIA due to their smaller size and greater charge
Boron Family
the metals are readily oxidized when heated in air
Boron Family
Hydroxides tend to show amphoteric properties [except for Boron (Boron trihydroxide - weak acid) and Thallium]
H3BO3
Orthoboric acid
Boron Family
B, Al, Ga, In, Tl, Nh
H2B4O7
Pyroboric Acid
HBO2
Metaboric Acid
Aluminum hydroxide (Al(OH)3)
Al3+ + 3NH4OH forms what white gelatinous precipitate