Alkenes and Alkynes Final (copy)
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39 Terms
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H20, H+, H3O
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1) Hg2, H2O / 2) NaBH4
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1) BH3 / 2) H2O2, NaOH
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Br2, H2O
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Br2
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O3
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H2, Lindlar (Pd, Ni)
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OsO4
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H-X (X = Br, Cl)
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H2, Lindlar (Pd, Ni)
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1) (sia)2 BH / 2) NaOH, H2O2
(sia)2 BH used for terminal alkynes. BH3 for internal alkynes.
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1) Br2 / 2) 3 (-)NH2 / 3) H2O
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(-)NH2 or NaH or LDA
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R - CH2 Br
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(on an alkyne) H20, H2SO4 or H30
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Chlorine free radical reaction
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Bromine free radical reaction
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19
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PBr3
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TsCl OR MsCl
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SOCl2
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Trimethylsilyl chloride
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TBAF (N+ 4butane, F-)
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mCPBA
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LiAlH4
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2° Jones
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1° Jones
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PCC
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HIO4
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Br2, hv
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Br2, hv
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HBr, peroxide (R-O-O-R)
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EtMgBr
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35
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HBr
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NaCN, H2O
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LiAlH4, H2O
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H+, MeSH
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H+, MeOH