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44 Terms
acid catalyzed hydration reagents
h+ (of sorts) and h2o
acid catalyzed hydration products
+oh (alcohols), markonvnikov
oxymercuration reagents
hg(oac), h2o2
oxymercuration demercuration products
alcohols, markovnikov
hydroboration oxidation reagents
bh3, thf, h2o2, h2o, oh-
hydroboration oxidation products
alcohols (anti markovnikov)
aromatic bromination/chlorination reagents
br2/albr3 or cl2/alcl3
aromatic bromination/chlorination products
new c-br or c-cl bond, benzene with halide attached
aromatic nitration reagents
hno3, h+
aromatic nitration products
c-no2 formed, benzene + no2 substituent
sulfunation of aromatics reagents
so3, h+
sulfunation of aromatics products
benzene + so3h substituent
friedel crafts alkylation reagents
alcl3 or fecl3, r-cl
friedel crafts alkylation products
benzene + r substituent (from r-cl)
friedel crafts acylation reagents
acyl chloride, alcl3
friedel crafts acylation products
benzene + ketone substituent
grignard reagents
mgbr-r
grignard products
carbon chain extension (r-mgbr length)
radical br reagents
br dot
benzylic position bromination reagents
benzylic c-h, hv, br2
benzylic bromination products
benzene + br free radical addition
benzylic oxidation reagents
kmno4, h+, heat
benzylic oxidation products
benzylic carboxylic acid
williamson ether synthesis reagents
o-r , alkyl halide
williamson ether synthesis products
haloalkane → sn2 rxn → ether
shapless epoxidation reagents
det (+ / -) , r-oh, ti(pr4)/ligand, tButoh
shapless epoxidation products
asymmetric epoxides
epoxidation reagents
mcpba, alkene
intramolecular halohydrins + alcohols products
epoxides
diels alder reagents
conjugated diene, dienophile
diels alder products
new 6 membered ring
making aldehydes
primary alcohol, pcc, oxidation reaction
making carboxylic acids
primary alcohols, chromic acid, oxidation reaction
acid catalyzed alcohol dehydration reaction
r-oh, h+ → results in double bonds
thiol/thioether formation reagents
r-halide, thiolate or ion (s-r/sh-)