Chem 2.2B: VSEPR Theory

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Chemistry

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6 Terms

1
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Tell me about Covalent Bonds

Every covalent bond is characterized by two values:

  • Bond length: the distance between bonded nuclei

  • Bond strength: the amount of energy needs to break the bond. It is also called bond enthalpy

In general, shorter bonds are stronger bonds

2
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Tell me about Multiple Bonds

Atoms, can share more than one pair of electrons to form multiple bonds.

  • double (2 pairs of electrons)

  • triple (3 pairs of electrons)

Multiple bonds have a greater number of shared electrons and so have a greater force of electrostatic attraction between the bonded nuclei

3
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Give me the order of bond length in from strongest to longest

Shortest | 3-bond<2-bond<1-bond | Longest

4
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Give me the order of bond enthalpy in from strongest to longest

Lowest | 1-bond<2-bond<3-bond | Highest

5
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What does VESPR mean? Tell me about it

Valence Shell Electron Pair Repulsion

  • electrons I covalent bonds and in lone pairs repel one another

  • Molecules have 3D shapes that place electron pairs on central atom as far apart as possible

  • involve electron domains

They depend on:

  1. The number of atoms bound to the central tom

  2. The number of lone pairs of electrons on the central atom

6
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Tell me about Electron Domains

  • can contain single, double or triple bonding electron pairs or non-bonding pairs of electrons

  • Total number of electron domains determine the geometric arrangements of electron domains

  • lone pairs of electrons have a higher concentration of charge and so have slightly more repulsion than bonding pairs