Material Science Test 1

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40 Terms

1
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What is the difference between a single crystal and polycrystal?

A single crystal has continuous lattice with one orientation; a polycrystal is composed of many grains with different orientations.

2
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What is polymorphism (allotropy)?

The ability of a material to exist in more than one crystal structure depending on temperature or pressure.

3
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What are grain boundaries?

Interfaces between crystals of different orientations; they disrupt lattice continuity and impede dislocation motion.

4
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What is the difference between small-angle and high-angle grain boundaries?

Small-angle boundaries (<15° misorientation) consist of dislocation arrays; high-angle boundaries have large misorientation and higher energy.

5
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What is an edge dislocation?

A line defect caused by an extra half-plane of atoms; Burgers vector is perpendicular to the dislocation line.

6
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What is a screw dislocation?

A line defect where atoms spiral around the dislocation line; Burgers vector is parallel to the dislocation line.

7
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What are mixed dislocations?

Dislocations with both edge and screw components.

8
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What are point defects?

Imperfections involving one or a few atoms, such as vacancies, interstitials, and substitutional atoms.

9
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What is a vacancy defect?

A missing atom in the lattice.

10
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What is an interstitial defect?

An extra atom positioned at a non-lattice site.

11
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What is a substitutional defect?

A foreign atom replaces a host atom in the lattice.

12
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What are area defects?

Two-dimensional imperfections such as grain boundaries, tilt boundaries, twin boundaries, and stacking faults.

13
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What is X-ray diffraction used for?

Determining crystal structures by applying Bragg's Law to measure atomic plane spacing.

14
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What is solidification?

The process of nucleation and growth during cooling, forming grains; faster cooling leads to smaller grains.

15
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What is the main difference between metals and ceramics?

Metals have metallic bonding, are ductile, and conductive; ceramics have ionic/covalent bonds, are brittle, and insulating.

16
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Which slip systems are preferred in FCC, BCC, and HCP structures?

FCC: many slip systems (ductile), BCC: less densely packed planes (stronger, less ductile), HCP: few slip systems (brittle).

17
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What is linear density?

The number of atoms per unit length along a crystallographic direction.

18
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What is planar density?

The number of atoms per unit area on a crystallographic plane.

19
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What are the 7 crystal systems?

Cubic, Tetragonal, Orthorhombic, Hexagonal, Trigonal (Rhombohedral), Monoclinic, Triclinic.

20
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What does the net energy vs interatomic distance curve show?

It shows balance between attractive and repulsive forces; the minimum indicates equilibrium bond length and bond energy.

21
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What are the three main categories of crystal defects?

Point defects, line defects (dislocations), and area defects.

22
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What is an edge dislocation?

A line defect caused by an extra half-plane of atoms; Burgers vector is perpendicular to the dislocation line.

23
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What is a screw dislocation?

A line defect where atoms spiral around the dislocation line; Burgers vector is parallel to the dislocation line.

24
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What is a mixed dislocation?

A dislocation that has both edge and screw character.

25
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What is a vacancy defect?

A missing atom from a lattice site.

26
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What is an interstitial defect?

An extra atom squeezed into a site not normally occupied in the lattice.

27
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What is a substitutional defect?

A foreign atom replaces a host atom in the lattice.

28
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What are grain boundaries?

Area defects where crystals of different orientations meet, disrupting lattice continuity.

29
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What is a small-angle grain boundary?

A boundary with misorientation <15°, usually composed of an array of dislocations.

30
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What is a high-angle grain boundary?

A boundary with misorientation >15°, higher energy, more disordered, and more diffusion-prone.

31
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What is a tilt boundary?

A special type of small-angle boundary formed by edge dislocation arrays.

32
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What are stacking faults?

Planar defects where the normal stacking sequence of crystal planes is interrupted.

33
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What are twin boundaries?

Planar defects where the crystal structure on one side is a mirror image of the other.

34
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APF formula?

APF = (Volume of atoms in unit cell) ÷ (Volume of unit cell).

35
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APF for Simple Cubic (SC)?

0.52

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APF for Body-Centered Cubic (BCC)?

0.68

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APF for Face-Centered Cubic (FCC)?

0.74 (highest)

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APF for Hexagonal Close-Packed (HCP)?

0.74 (same as FCC)

39
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Which structures are most efficient?

FCC and HCP.

40
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Which structure is least efficient?

Simple Cubic (rare in nature).