Thermochemistry

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Flashcards covering key vocabulary terms and definitions related to thermochemistry.

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17 Terms

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Chemical energy

The energy stored in the bonds of chemical compounds.

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Thermochemistry

The study of heat changes that occur during chemical reactions.

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Energy

The capacity to do work or transfer heat.

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First Law of Thermodynamics

Energy is neither created nor destroyed; it can only be transformed from one form to another.

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Enthalpy (H)

The heat content of a system, defined as the internal energy plus the product of pressure and volume.

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Calorimetry

An experimental technique for measuring the amount of heat involved in a chemical reaction.

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Hess’s Law

A law stating that the total enthalpy change for a reaction is the sum of the enthalpy changes for individual steps.

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Bond Enthalpy (D)

The energy required to break one mole of a bond in a gaseous substance.

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Kinetic energy (KE)

Energy possessed by an object due to its motion.

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Potential energy (PE)

Stored energy in an object due to its position or condition.

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Specific heat capacity (Cs)

The amount of heat required to raise the temperature of 1 gram of a substance by 1 °C.

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Standard enthalpy of formation (ΔHf °)

The change in enthalpy when one mole of a compound is formed from its elements in their standard states.

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Exothermic reaction

A process that releases heat to the surroundings.

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Endothermic reaction

A process that absorbs heat from the surroundings.

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Internal Energy (E)

The total energy contained within a system, including both kinetic and potential energy.

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State function

A property that depends only on the current state of the system, not on the path taken to reach that state.

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Work (w)

Energy transfer associated with a force acting through a distance.