structure and bonding

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17 Terms

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ionic bonding
between metals and non metals, one atom loses an electron and one gains one (e.g. NaCl), opposite charged ions attract each other and bond by electrostatic forces
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ionic lattice
structure made up of regular pattern of ionic bonds
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why do ionic compounds have high melting/boiling points?
electrostatic forces of attraction between the ions are strong so it takes a lot of energy to overcome them
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why can ionic compounds conduct electricity when in liquid state but not solid state?
when in liquid state, the ions are free to move but in solid state, the ions are stuck :(
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simple covalent bonding
between non metals, pair of electrons shared between atoms (e.g. CO2 which has a double bond)
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why do simple covalent structures have low melting/boiling points?
there is not much energy needed to overcome the weak intermolecular forces between the molecules the actual covalent bonds are not broken)
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why are simple covalent structures such bad conductors?
they don’t have an overall charge as they don’t contain any charged particles
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giant covalent structures
many atoms joined by covalent bonds
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metallic bonding
between metals, sea of dealocalised electrons and atoms arranged in regular pattern, sharing of delocalised electrons creates strong metallic bonds
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why are metals good conductors?
delocalised electrons carry charge through the metal (good conductors of thermal energy because delocalised electrons transfer energy)
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why do metals have high melting and boiling points?
because large amounts of energy are needed to overcome the strong metallic bonds
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why are alloys harder and stronger than pure metals?
contain atoms of other elements, atoms have different sizes, so they distort the layers of atoms in the pure metal, this means that a greater force is required for the layers to slide over each other
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why do giant covalent structures have high boiling/melting points?
large amounts of energy are needed to overcome the strong covalent bonds
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why are giant covalent structures bad conductors?
have no free charged particles BUT graphite is an exception as it has delocalised electrons
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converting from nm to cm
x by 10000000
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polymers
large molecules joined by covalent bonds
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why do polymers have high boiling/melting points?
a high amount of energy is needed to overcome the strong intermolecular forces