Orgo 1 Exam 3

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Last updated 2:34 PM on 7/15/26
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6 Terms

1
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<p>Hydrohalogenation</p>

Hydrohalogenation

Markovnikov: Br or (X) goes on more substituted carbon of double bond. H goes to less subst.

<p>Markovnikov: Br or (X) goes on more substituted carbon of double bond. H goes to less subst.</p>
2
New cards
<p>1,2 - hydride shift</p>

1,2 - hydride shift

NOT on double bond, Cl to most subst. carbon

formation of a more stable carbocation

<p>NOT on double bond, Cl to most subst. carbon</p><p>formation of a more stable carbocation</p>
3
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<p>1,2 - alkyl shift</p>

1,2 - alkyl shift

NOT on double bond, Br to most subst. carbon

<p> NOT on double bond, Br to most subst. carbon</p>
4
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<p>Hydrohalogenation (ring expansion)</p>

Hydrohalogenation (ring expansion)

Markovnikov
4 or 5 sided, allylic double bond usually

<p>Markovnikov<br>4 or 5 sided, allylic double bond usually</p>
5
New cards
<p>acid-catalyzed hydration</p>

acid-catalyzed hydration

Alcohol + hydronium

<p>Alcohol + hydronium</p>
6
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<p>addition of Br or Cl</p>

addition of Br or Cl

anti addition (180) when given possibility to be trans.
if not, racemix mixture

<p>anti addition (180) when given possibility to be trans. <br>if not, racemix mixture</p>