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sp3
all 4 orbitals are hybridised
the 2 orbitals are in between and never on the axis and combine into a tetrahedral structure
used when you have 4 separate bonds
sp2
3 hybridised orbitals, 1 unhybridized
associated with double bonding as 2 different types of bonds (sigma and pi) are formed with different overlaps, and this does not require the same level of hybridisation. the unhybridized orbital forms the pi bond in the double bond
associated with trigonal planar shape
arises when you have a double bond and 2 single
sp
2 hybridised orbitals, 2 unhybridized
occurs when you either have 2 double bonds or a single and a triple bond. this means 2 pi bonds are required, formed by the 2 unhybridized orbitals
associated with linear shape
hybridisation
hybridisation is a mixing of atomic orbitals used to produce hybrid orbitals used in bonding
the electron in the 2s orbital is excited and occupies a vacant 2p orbital. the orbitals then become degenerate (have the same energy)/hybridise with the 2s orbital. the total energy stays the same, but the energy of each orbital is in between 2s and 2p
hybridized orbitals change shape, unhybridized retain their shape
lone pairs of electrons can exist in hybrid orbitals and contribute towards the shape (done according to edg)