alkene reactions

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Last updated 4:34 AM on 6/15/26
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12 Terms

1
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reactant: O3

molecule cleaves in half across double bond with two oxygens attached to each side, no stereochem, no Mark/anti-Mark

<p>molecule cleaves in half across double bond with two oxygens attached to each side, no stereochem, no Mark/anti-Mark</p>
2
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reactant: KMnO4, cold and dilute

2 OH groups added across double bond
syn addition

<p>2 OH groups added across double bond<br>syn addition</p>
3
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reactants: OsO4

syn addition of 2 OH groups across the double bond

4
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reactants: MCPBA/peracid

2 OH added

anti addition

5
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reactants: H2 / Pt catalyst or Ni

syn addition of H across double bond to make alkane

6
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reactants: BH3TF / H2O2 or H2O or NaOH

syn addition of OH and H

anti-Markovnikov addition of OH

<p>syn addition of OH and H</p><p>anti-Markovnikov addition of OH</p>
7
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reactants: HX2

Markovnikov addition of halogen

8
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reactants: Br2 / H2O

Markovnikov addition of OH

anti addition of Br and OH

<p>Markovnikov addition of OH</p><p>anti addition of Br and OH</p>
9
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reactant: ROOOR / hv / HBr or Br2

no stereochemistry/markovnikov at all, depends on Zaitsev/Hoffman

<p>no stereochemistry/markovnikov at all, depends on Zaitsev/Hoffman</p>
10
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reactants: Hg(OAc)2 / NaBH4

Markovnikov addition of OH

<p>Markovnikov addition of OH</p>
11
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reactant: Br2

2 Br anti addition on the alkene carbons

12
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reactant: H2SO4

H and OH added

OH added markovnikov