Chemistry - Chapter 34: Nitrogen and its compounds

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Last updated 3:22 AM on 4/2/25
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14 Terms

1
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Mechanism of formation of amines from halogenalkane and ammonia (NH3)

Nucleophilic substitution

2
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Condition for formation of amines from halogenoalkane and ammonia (NH3)

Hot ethanolic ammonia (NH3) under pressure

3
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Mechanism of formation of amines from halogenoalkane and nitrile (CN)

Nucleophilic Substitution AND addition

4
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Condition of formation of amines from halogenoalkane and nitrile (CN)

Step 1: KCN, ethanol heat under reflux
Step 2: LiAlH4 / Ni catalyst, nitrile vapour, hydrogen in ether

5
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Mechanism for formation of amines from halogenoalkane and other amines

Nucleophilic substitution

6
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Condition for formation of amines from halogenoalkane and other amines

Ethanol, seal tube, heat under reflux

7
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Mechanism of formation of amines from reduction of amides

Addition and reduction

8
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Condition for formation of amines by reduction of amides

LiALH4/ Ni catalyst in dry ether

9
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Mechanism of reaction between amines and acyl chlorides to form amides

Addition - elimination

10
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Condition of reaction between acyl chloride and amine to form amide

NH3 concentrated, room temperature

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Mechanism of reaction of amides to produce COOH or COONa

Hydrolysis

12
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Condition of reaction of amides to form COOH or COONa

Reflux with acid or base

13
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Mechanism of production of phenylamine from nitrobenzene

Reduction

14
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Condition of production of phenylamine from nitrobenzene

Hot tin (Sn), concentrated HCl then NaOH