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Flashcards for Chapter 10: Liquids and Solids
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Intermolecular Forces (IMFs)
Forces of attraction between molecules
Dispersion Forces (London)
Present in all molecules; arise from temporary dipoles.
Dipole-Dipole
Between polar molecules
Hydrogen Bonding
Strongest van der Waals force; H bonded to N, O, or F.
Viscosity
Resistance to flow
Surface Tension
Energy to increase liquid surface area.
Cohesion
Attraction between like molecules.
Adhesion
Attraction between unlike molecules.
Capillary Rise
Liquid rises/falls in narrow tubes based on cohesion/adhesion.
Vaporization
Liquid → Vapor
Condensation
Vapor → Liquid
Vapor Pressure
Pressure from vapor at equilibrium
Boiling Point
Occurs when vapor pressure = external pressure.
ΔHvap
Heat needed to vaporize a substance.
ΔHfus
Heat needed to melt a substance.
Phase Diagrams
Show phase of a substance under different temperature/pressure.
Triple Point
All three states coexist.
Critical Point
Above this, no distinct liquid/gas; supercritical fluid forms.
Crystalline
Ordered (e.g., salt, diamonds).
Amorphous
Disordered (e.g., glass, plastic).
Molecular Solid
Soft, low melting points (e.g., Ice, CO₂)
Ionic Solid
Hard, high melting points (e.g., NaCl)
Metallic Solid
Malleable, conductive (e.g., Fe, Cu)
Covalent Network Solid
Very hard, high melting points (e.g., Diamond, SiO₂)