Hydrocarbons

What type of reaction is fluorination? What does it give us?

It is a highly exothermic and uncontrollable reaction which gives carbon black and HF

What is the experimental ratio of reactivity for chlorination??

1° : 2° : 3° = 1 : 3.85 : 5

What is the experimental ratio of reactivity for Bromination??

1° : 2° : 3° = 1 : 82 : 1600

What is the general formula for complete combustion

What reactants cause controlled oxidation reactions?

Cu and Mo₂O₃

What are the conditions for aromatization of skeletal compounds

773K, 10 - 20 atm

What is pyrolysis?

It is the breaking down of compounds in the absence of air

Why cant we see any shifts in 3 and 6 rings?

3 → Dancing resonance

6 → Its stable that way

What is the other name for markonikov’s rule?

Kharash effect

What is the temperature and state of
C1 → C4

C5 → C17

C18 → C18+

TEmp = 298 Kelvin

1. gases

2. liquids

3. solids

What is the formula for Baeyer’s reagent?

It is the cold, dilute solution of KMnO4

What are the reagents that are used in reductive ozonolysis?

1. O3 + CCl4

2. Zn

3. Zn+H2O

4. Me2S

What are the reagents that are used in oxidative ozonolysis?

1. O3 + CCl4

2. H2O

3. H2O2

What are all the ways which we can prepare Alkynes through hydrolysis? What are some compounds that do not undergo hydrolysis?

What salts are used in kolbe’s electrolysis method?

Sodium and Lithium

What are the compounds that we use as tests in order to check the saturation and position of alkynes?

1. Silver Nitrate test → Ammonical Silver Nitrate

2. Cuprous Chloride test → Cu2Cl2+NH4OH

What are the reagents used to get SO3 electrophile?

1. H2S2O7

2. Fuming/conc.H2SO4

3. SO3+H2SO4

What are the common names for this compound?

What is the wheeland intermediate?

Sigma complex