Polar bonds and electronegativity

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12 Terms

1
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What is electronegativity?

The power of an atom to attract the bonding pair of electrons in a covalent bond.

2
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What is the trend for electronegativity across a period?

It increases left to right, with fluorine being the most electronegative.

3
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What is the trend for electronegativity along a group?

It increases up a group.

4
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What does it mean for an atom to be delta positive?

Electrons are pulled more to the end of an atom making it slightly positive.

5
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What does it mean for an atom to be delta negative?

Electrons are pulled more to the end of an atom making it slightly negative.

6
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What is a permenant dipole?

The difference in charge between two atoms involved in a covalent bond due to the attraction of the electron pair by the more electronegative atom.

7
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How are electrons in a polar molecule distributed?

Asymmetrically, causing a permenant dipole.

8
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How are electrons in a non-polar molecule distributed?

Symmetrically, with no permenant dipole.

The bond between the atoms is pure covalent.

9
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How can you make predictions that an atom is going to be polar?

-Molecules with symmetrical shapes tend to be polar

-Molecules with OH, H and N at the end tend to be non-polar

10
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How can you predict when a molecule is going to be non-polar?

-Molecules containing carbon tend to be non-polar.

-Diatomic elements tend to be non-polar.

11
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What are the features of non-polar molecules?

-Contain no polar bonds

-Contain some polar bonds but the delta charges cancel each other out so no permenant dipole is formed.

12
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What are the features of polar molecules?

-Contain asymmetrical polar bonds