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Crystals
They are formed from solution, melts, and vapors.
Pressure
Temperature
Concentration
What are the 3 Factors of crystallization?
Nucleation
It is the initial stage of crystal growth. It forms nucleus as a result of chemical bonding of various ion.
Formation of crystal structure/crystal faces
It is a result of the continuous growth from a nucleus that exhibits highly-ordered crystalline structure.
Formation of Euhedral Crystal
It is a result of the continuous growth of a nucleus that exhibits euhedral crystal - well-defined crystal boundary.
Intergrowths of Crystals
It refers to the occurrence of one or more crystals in the same mineral.
Crystal Twinning
Other term for intergrowth of crystals:
Crystal Twinning
Sometimes during the growth of a crystal, or if the crystal is subjected to stress or temperature/pressure conditions different from those under which it originally formed, two or more intergrown crystals are formed in a symmetrical fashion.
Reflection
Rotation
Inversion
What are the 3 symmetry Operations that Define Twinning?
Twin plane
Reflection across a mirror plane. The added mirror plane would then be called a _______________.
Twin Axis
Rotation about an axis or line in the crystal. The added rotation axis would then be called a ____________.
Twin Center
Inversion through a point. The added center of symmetry would then be called a _____________.
Twin laws
Are expressed as either form symbols to define twin planes (i.e. (hkl]) or zone symbols to define the direction of twin axes (i.e. [hkl]).
Composition surface
The surface along which the lattice points are shared in twinned crystals is called a __________________.
always parallel
never parallel
the twin plane is _____________________ to a possible crystal face and ______________________ to an existing plane of symmetry (remember that twinning adds symmetry).
Contact Twins
They have a planar composition surface separating 2 individual crystals.
Contact Twins
Are usually defined by a twin law that expresses a twin plane (i.e. an added mirror plane).
Penetration Twins
They have an irregular composition surface separating 2 individual crystals.
Penetration Twins
These are defined by a twin center or twin axis.
Polysynthetic Twins
Twins whose composition surfaces are parallel to one another.
Cyclical Twins
Twins whose composition surfaces are not parallel to one another
Albite Law
- Type of polysynthetic twinning (e.g., plagioclase)
- The twin law [010] indicates that the twining occurs perpendicular to the b crystallographic axis.
Albite Law
Is a type of crystal twinning, specifically in plagioclase feldspars, characterized by parallel, thin lamellae (striations) on the basal plane.
Pericline Law
It describes a specific type of crystal twinning where the twin axis is the b-axis, typically occurring in microcline feldspar.
Pericline twinning
It occurs as the result of monoclinic orthoclase or sanidine transforming to microcline. It usually occurs in combination with albite twinning in microcline but is only observable with the polarizing microscope.
tartan twinning
The combination of pericline and albite twinning produces a cross-hatched pattern, called __________________.
Manebach Law
- Type of contact twinning
- It forms a contact twin commonly observed in the mineral orthoclase.
- This twinning is very diagnostic of orthoclase when it occurs.
Carlsbad Law
- Type of penetration twinning
- It shows two intergrown crystals, one rotated 180º from the other about the [001] axis.
Carlsbad twinning
Is the most common type of twinning in orthoclase and is thus very diagnostic of orthoclase when it occurs.
Braveno Law
This type of twinning occurs in minerals like orthoclase, where two intergrown crystals are separated by a planar surface.
Baveno Law
- Type of contact twinning
- Twin plane at {021}
Swallowtail Law
- Type of contact twinning
- Twin plane at {100}
- Commonly occurred in gypsum
Staurolite Law
Occurring in monoclinic mineral but has an appearance of an orthorhombic minerals.
Calcite Law
Occurs as polysynthetic twins that result from deformation.
calcite crystals.
The two most common twin laws that are observed in ___________________.
Brazil Law
Occurs at {112̅ 0} - is a penetration twin that results from transformation.
Dauphine Law
Occurs at [0001} - is a penetration twin that results from transformation.
Japanese Law
Occurs at {112̅ 2} - is a penetration twin that results from accidents during growth.
Spinel Law
It is a twin plane at {1̅ 1̅ 1}, parallel to an octahedron that occurs commonly in mineral spinel.
Iron Cross Law
The mineral pyrite (FeS₂) often shows the iron cross made of the interpenetration of two pyritohedrons.
Mineral Stability/Phase Diagram
It is a graphical representation of chemical equilibrium that shows the behavior of solids, liquids and gases under variable external condition, such as those of temperature and pressure.
external conditions
Phase diagrams are very useful in providing a visual image of what a mineral or group of minerals is stable with respect to some other mineral or mineral groups at a specific set of ___________________.
Lever Rule
A mathematical expression by which the relative phase amounts in a two-phase alloy at equilibrium may be computed.
Physical Properties
It is fundamentally controlled by the crystal structure and chemical composition of the mineral
Interaction with Light
Mass-Dependent Properties
Shape
Properties Related to Mechanical Cohesion
Magnetic and Electrical Properties
What are the 5 Common Physical Properties of minerals?
Color
Luster
Streak
Luminescence
Diaphaneity
Common Physical Properties under Interaction with Light:
Visible Light
A segment of the electromagnetic spectrum that the human eye perceives.
Monochromatic Light
Consists of a single wavelength as one of the spectral colors
Polychromatic Light
Consists of more than one wavelength
Complementary Colors
Refers to the combination of two colors
Mineral Color
Refers to our perception of wavelengths of light that are reflected from or refracted through the mineral
Selective absorption
Process by which a material absorbs some components of visible light and transmits others.
Selective absorption
Describes how electrons in each atom in the crystal structure interact with light
Impurities
Refers to the elements (e.g., Ti, V, Cr, Mn, Fe, Co, Ni, Cu...) that are not present in the pure compound.
Corundum (Al2O3)
(1) Mineral Color: Colorless
Ruby (Al2O3 Cr)
Mineral Color: Pinkish Red to Blood Red
Sapphire (Al2O3 Fe, Ti)
Mineral Color: Blue
Amethyst (SiO2. Fe³)
Mineral Color: Purple
Quartz (SiO2)
(2) Mineral Color: Colorless
Tarnish
It is a property in certain minerals that cause them to discolor when placed in certain environments.
Diaphaneity
Refers to a mineral that can transmit light
Opaque
Impossible to see through; no light is transmitted
Translucent
when light, but not an image is transmitted
Transparent
When both light and image are visible
Luster
It refers to the general appearance of the mineral surface in reflected light
Metallic
minerals that have the appearance of a metal
Submetallic
minerals with a metallic appearance but develop a dull coating or tarnish
Non-Metallic
minerals that do not have the appearance of a
metal
Vitreous
Minerals that exhibit glassy appearance
Resinous
Minerals that appear like resin
Pearly
Minerals that appear like pearls where their surfaces are parallel to well-developed cleavage planes
Greasy
Minerals that appear as though covered with a thin layer of oil which results from light scattered by microscopically rough surfaces
Silky
Minerals that exhibit a skein of silk or a piece of satin which are characteristics of some fibrous minerals
Earthy
Minerals that have dull surfaces that lack any shine and are generally seen with aggregates of very fine mineral grains
Adamantine
Minerals that appear with brilliant luster like glass commonly exhibited by minerals harder than the streak plate
Streak
Describes the color of the mineral in powdered form and can also help distinguish between minerals with metallic and nonmetallic luster
dense, dark
light-colored
Metallic minerals have a _______________ streak.
Nonmetallic minerals have a ___________ streak
Play of Colors or Iridescence
Refers to the series of colors due to the interference of light either at the surface or in the interior of a mineral as the angle of the incident of light changes
Adularescence (Schiller)
It is best described as a milky, bluish luster or glow originating from below the surface of the mineral
Labradorescence
Refers to a peculiar reflection of the light from sub-microscopical planes orientated in one direction (rarely in two directions)
Aventurescence
Refers to a metallic glitter, arising from minute, preferentially oriented mineral platelets within the mineral
Chatoyancy or AKA Cat's Eye Effect
It shows a band of light at right angles to the length of the fibers or the direction of the inclusion which commonly occurring on fibrous minerals with closely packed parallel fibers or from a parallel arrangement of inclusions or cavities.
Asterism
- Crystals that exhibit triple chatoyancy, that is, one beam of light at right angles to each direction of the inclusions producing a six-pointed star which is a result of the scattering of light from inclusions of rutile arranged in three crystallographic directions.
Luminescence
Refers to the emission of light by a mineral that is not a direct result of incandescence
impurity ions activators
Luminescence is usually observed in minerals containing __________________ and can only be seen in the dark.
Fluorescence
It is where the energy is supplied by electromagnetic radiation typically caused by UV light
Phosphorescence
Refers to the delayed luminescence or "afterglow".
Density
Specific Gravity
Common Physical Properties under Mass-Dependent Properties:
Density
Refers to the mass of the mineral per unit volume
Specific Gravity
Refers to the ratio of the density of the mineral to the density of water (~1.0 g/cm³)
Crystal Form
It consists of a group of crystal faces, all of which have the same relation to the elements of symmetry
Euhedral
It describes a mineral that is completely bounded by crystal faces and whose growth during crystallization was not restrained or interfered with by adjacent crystals or mineral grains
Subhedral
It describes a mineral grain that is partly bounded by crystal faces and partly by surfaces formed against preexisting grains
Anhedral
It describes a mineral that lacks crystal faces and that may show rounded or irregular surfaces produced by the crowding of adjacent minerals during crystallization
Habit
It describes the general shape and irregularities of the crystal
Crystal Habit
Describe the shape of each crystal
Aggregate Habit
Describe the shape of the group or assemblage of similar crystals
Fibrous
Parallel arrangement of acicular or filiform crystals
Radiating
Acicular-filiform crystals radiating outward from a central point
Divergent
Prismatic crystals diverging from a common area