EXPERIMENT 1 Molar Enthalpy of Fusion for Ice

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Vocabulary flashcards covering key concepts, terms, and equations related to the molar enthalpy of fusion, heating curves, and related thermochemistry from Experiment 1.

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16 Terms

1
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Molar enthalpy of fusion

The amount of heat required to convert one mole of a solid (ice) into a liquid (water) at the substance's melting point, under constant pressure.

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Enthalpy of fusion

The heat needed to melt one mole of a substance from solid to liquid at its melting point.

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Heating curve

A graph of temperature versus time that shows how a substance heats and undergoes phase transitions.

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Phase transition

A change of a substance from one phase to another (solid ↔ liquid, liquid ↔ gas) that often involves heat transfer.

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Specific heat

The amount of heat required to raise the temperature of 1 g of a substance by 1 °C (units: J g^-1 °C^-1).

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2.09

Specific heat of ice

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4.184

Specific heat of liquid water

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2.0

Specific heat of steam

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∆H_fus

Molar enthalpy of fusion (heat required to melt one mole of a substance).

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∆H_vap

Molar enthalpy of vaporization (heat required to vaporize one mole of a substance).

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Calorimeter

A device (e.g., coffee cup calorimeter made of Styrofoam) used to measure heat transfer during a chemical process.

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Ice-to-water melting

Phase transition from solid to liquid; requires energy input at a constant temperature.

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Plateau (on a heating curve)

Flat region indicating a phase transition where temperature remains constant while heat is absorbed or released.

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Molar enthalpy of fusion for ice

A constant value at the melting point for ice, used to compare energy requirements per mole across substances.

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Molar mass of water

18.02 g per mole of H₂O.

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Vaporization enthalpy of water at 100 °C

44.0 kJ mol^-1; the heat required to vaporize one mole of water at 100 °C.