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equation relating energy of a system
ΔU = Q- P ΔV
entropy
ΔS=Q/T
where Q is heat(energy flow)
enthalpy
ΔU = Q-PΔV which can be expanded to a useful equation:
ΔH=Q at constant pressure
Gibbs free energy definition
quantifies if a reaction will occur spontaneously or not
spontaneous or non spontaneous if ΔS<0
non spontaneous
spontaneous or non spontaneous if ΔS>0
spontaneous
spontaneous or non spontaneous if ΔH>0
heat absorbed-non spontaneous
spontaneous or non spontaneous if ΔH<0
heat produced - spontaneous
Gibbs free energy equation
ΔG=ΔH-TΔS
first law of thermodynamics in relation to the cell
ΔU=Q+W
boltzmanns microscopic definition of entropy
S=k ln(Ω)
where Ω is the number of possible configurations of a systemst
ructural requirements of membrane bilayer
semi porous
flexible and deformable
strong enough to withstand external forces and energy fluctuation
surface tension
y = energy/area J/m²
compression energy of bilayer