Chapter 5 - Electronic Structure & Periodic Properties

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15 Terms

1

What is ionization energy?

The energy required to remove one electron from an atom.

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2

What principle allows us to understand that no two electrons in an atom have the same set of quantum numbers?

Pauli Exclusion Principle.

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3

What is screening in the context of electron energies?

The partial cancellation of electron-proton attraction due to electron-electron repulsion.

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4

How does atomic radius generally change across a period and down a group in the periodic table?

Atomic size decreases from left to right and increases from top to bottom.

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5

What is the Aufbau principle?

Electrons are placed into atomic orbitals beginning with the lowest-energy orbitals.

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6

What is the definition of valence electrons?

Electrons that are spatially and energetically accessible, which determine the chemical properties of an atom.

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7

Describe how ionization energy trends in the periodic table.

Ionization energy increases going up and across to the right of the periodic table.

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8

Which orbitals are filled first according to the Aufbau principle?

Lowest energy orbitals are filled first before higher energy orbitals.

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9

What is the formula for lattice energy?

The energy released when an ionic solid decomposes into gaseous ions.

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10

What distinguishes between valence electrons and core electrons?

Valence electrons participate in chemical reactions, while core electrons do not.

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11

Which elements deviate from the expected electron configurations based on the Aufbau principle?

Chromium (Cr) and Copper (Cu).

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12

What is periodicity in relation to the periodic table?

Periodic patterns that provide information about electron arrangements in atoms.

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13

What effect does increased nuclear charge have on ionization energy?

Increased nuclear charge generally leads to increased ionization energy.

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14

What is electron affinity?

The energy change when an electron is added to an atom.

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15

How do the atomic sizes of cations and anions compare to their neutral atoms?

Cations are smaller, and anions are larger than their corresponding neutral atoms.

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