Quantum Mechanics and Periodic Table Flashcards

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Flashcards for vocabulary related to quantum mechanics and the periodic table.

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26 Terms

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Electromagnetic Radiation

Light that travels in the form of waves; all different types together are called the Electromagnetic Spectrum (EMS).

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Wavelength

The distance between two successive crests/troughs, measured in meters or nanometers.

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Frequency

The number of waves that pass a certain point per second, measured in seconds or Hertz (Hz).

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Photoelectric Effect

The phenomenon where certain amounts of light energy strike the surface of a metal.

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Quantum

A packet of energy that light can carry.

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Planck's Constant

Constant (h) that relates energy to frequency; h = 6.626 x 10^-34 J*sec

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Photon

A particle of light that carries energy in units of quanta and has no mass.

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Emission Spectra

The unique wavelengths of light seen as small bars of color when electrified light passed through a gas is sent through a prism; wavelength is unique for each element.

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Ground State

The lowest energy state of an electron.

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Excited State

A higher energy state that an electron temporarily occupies after gaining energy.

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Uncertainty Principle

It is impossible to know the exact location and position of an electron simultaneously.

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Orbital

A specific region within the electron cloud where there is a 90% chance of finding an electron.

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Principle Quantum Number (n)

Indicates the energy level or shell of an electron and its size; possible values are positive whole numbers (1, 2, 3, etc.).

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Orbital Quantum Number (l)

Indicates the energy sublevel or subshell of an electron; possible values range from 0 to n-1 and corresponds to the shape of the orbital.

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Magnetic Quantum Number (ml)

Indicates a specific orbital and corresponds to the number of orbitals possible in a sublevel; possible values range from -l to +l.

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Spin Quantum Number (ms)

Indicates the specific spin of an electron; possible values are +1/2 and -1/2.

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Aufbau Principle

Electrons occupy the lowest energy levels first.

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Pauli Exclusion Principle

No two electrons in an atom can have the same set of 4 quantum numbers; within an orbital, electrons must have opposite spin.

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Hund's Rule

Electrons occupy degenerate orbitals (orbitals of the same energy) with one electron each before pairing will occur.

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Valence Electrons

Electrons in the highest occupied energy level (outermost level) for an atom.

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Periods/Series

Horizontal rows on the periodic table; indicate the energy level.

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Groups/Families

Vertical columns on the periodic table; clues to chemical behavior.

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Atomic Radius

A measure of ½ the distance across an atom.

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Ionic Radius

The radius of an atom's ion; smaller for cations (formed by losing electrons), larger for anions (formed by gaining electrons).

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Ionization Energy (IE)

The energy required to remove a valence electron from an atom.

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Electronegativity (EN)

The ability of an atom to attract a bonded pair of electrons to itself.