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Alkane

Alkene

Alkyne

Benzene Ring / Aromatic / Phenol

Amine

Alcohol

Ether

(Or any halogen)
Alkyl Halide

Thiol

Aldehyde

Keytone

Ester

Carboxylic Acid

Amide
Constitutional isomers
Have the same molecular formula but different connectivity
Stereoisomers
Have the same molecular formula, same connectivity, but different three-dimensional orientation

nσπ

πσv

vσn

σπn

πσπ
pKa of H2O
15.7

Anti

Gauche

Eclipsed